From Geospatial World: “Google and DeepMind predict wind energy output using AI”

From Geospatial World

03/04/2019
Aditya Chaturvedi

Image Courtesy: Unsplash

Google has announced in its official blog post that it has enhanced the feasibility of wind energy by using AI software created by its UK subsidiary DeepMind.

Renewable energy is the way towards lowering carbon emissions and sustainability, so it is imperative that we focus on yielding optimum energy outputs from renewable energy.

Renewable technologies will be at the forefront of climate change mitigation and addressing global warming, however, the complete potential is yet to be harnessed owing to a slew of obstructions. Wind energy has emerged as a crucial source of renewable energy in the past decade due to a decline in the cost of turbines that has led to the gradual mainstreaming of wind power. Though, unpredictability in delivering power at set time frame continues to remain a daunting challenge before the sector.

Google and DeepMind project will change this forever by overcoming this limitation that has hobbled wind energy adoption.

With the help of DeepMind’s Machine Learning algorithms, Google has been able to predict the wind energy output of the farms that it uses for its Green Energy initiatives.

“DeepMind and Google started applying machine learning algorithms to 700 megawatts of wind power capacity in the central United States. These wind farms—part of Google’s global fleet of renewable energy projects—collectively generate as much electricity as is needed by a medium-sized city”, the blog says.

Google is optimistic that it can accurately predict and schedule energy output, which certainly would have an upper hand over non-time based deliveries.

Image Courtesy: Google/ DeepMind

Taking a neural network that makes uses of weather forecasts and turbine data history, DeepMind system has been configured to predict wind power output 36 hours in advance.

Taking a cue from these predictions, the advanced model recommends the best possible method to fulfill, and even exceed, delivery commitments 24 hrs in advance. Its importance can be estimated from the fact that energy sources that deliver a particular amount of power over a defined period of time are usually more vulnerable to the grid.

Google is working to make the algorithm more refined so that any discrepancy that might occur could be nullified. Till date, Google claims that Machine Learning algorithms have boosted wind energy generated by 20%, ‘compared to the to the baseline scenario of no time-based commitments to the grid’, the blog says.

Image Courtesy: Google

Completely doing away with wind variability is next to impossible, but Google claims that Machine Learning and AI would indeed make wind power more predictable and hence more useful.

This unique approach would surely open up new avenues and make wind farm data more reliable and precise. When the productivity of wind power farms in greatly increased and their output can be predicted as well as calculated, wind will have the capability to match conventional electricity sources.

Google is hopeful that the power of Machine Learning and AI would boost the mass adoption of wind power and turn it into a popular alternative to traditional sources of electricity over the years.

See the full article here .

five-ways-keep-your-child-safe-school-shootings

Please help promote STEM in your local schools.

Stem Education Coalition

http://www.geospatialworld.net

With an average of 55,000+ unique visitors per month, http://www.geospatialworld.net is easily the number one media portal in geospatial domain; and is a reliable source of information for professionals in 150+ countries. The website, which integrates text, graphics and video elements, is an interactive medium for geospatial industry stakeholders to connect through several innovative features, including news, videos, guest blogs, case studies, articles, interviews, business listings and events.

600,000+ annual unique visitors

From Science Alert: “14-Year-Old Kid Has Reportedly Become The Youngest Person to Achieve Nuclear Fusion”

From Science Alert

22 FEB 2019
CARLY CASSELLA

(Fox News)

We might have a new contender for the youngest person to ever achieve nuclear fusion.

Tennessee teenager Jackson Oswalt is not your average 14-year-old. While other kids are playing video games or watching TV, he’s been busy putting together a nuclear laboratory in an old playroom in his house.

The budding nuclear engineer has been working on this project since he was 12, and on 19 January 2018, just hours before his 13th birthday, he reportedly achieved his mission.
Using 50,000 volts of electricity, Oswalt was reportedly able to combine two atoms of deuterium gas, successfully fusing the nuclei in his reactor’s plasma core.

(Jackson Oswalt)

After conducting some further tests over the following months, Oswalt became more convinced than ever that he had achieved fusion.

“For those that haven’t seen my recent posts, it will come as a major surprise that I would even consider believing I had achieved fusion,” he wrote on the Fusor.net forum recently.

“However, over the past month I have made an enormous amount of progress resulting from fixing major leaks in my system. I now have results that I believe to be worthy.”

To be clear, these claims have not been peer reviewed as yet – until they’re replicated and the results are published in a peer-review journal, we need to take all of this with a very, very big grain of salt.

But Oswalt is not the only one who thinks he’s been successful.

The Open Source Fusor Research Consortium has also verified Oswalt’s results. According to Jason Hull, an administrator on the website, Oswalt has now been added to the hobbyist group’s list of successful fusioneers.

“Good work. Nice system. You have put some money into this,” Hull wrote, applauding Oswalt’s work.

He’s not wrong. While Oswalt’s nuclear reactor is considered a “tiny volume fusor”, setting it up in an old playroom in his parents’ house cost something like $10,000 (£7,700).

What’s even crazier is that Oswalt isn’t the only young teen working on ambitious projects like this.

If Oswalt’s results are peer-reviewed or verified by a scientific organisation, he will have officially ousted the former record holder, a 14-year-old named Taylor Wilson, as the youngest person to ever achieve nuclear fusion.

See the full article here .

five-ways-keep-your-child-safe-school-shootings

Please help promote STEM in your local schools.

Stem Education Coalition

From The Conversation: “Utilities are starting to invest in big batteries instead of building new power plants”

From The Conversation

February 22, 2019
Jeremiah Johnson
Associate Professor of Environmental Engineering
North Carolina State University

Joseph F. DeCarolis
Associate Professor of Environmental Engineering
North Carolina State University

Utilities are starting to invest in big batteries instead of building new power plants. This is what a 5-megawatt, lithium-ion energy storage system looks like. phys.org
Credit: Pacific Northwest National Laboratory.

Due to their decreasing costs, lithium-ion batteries now dominate a range of applications including electric vehicles, computers and consumer electronics.

You might only think about energy storage when your laptop or cellphone are running out of juice, but utilities can plug bigger versions into the electric grid. And thanks to rapidly declining lithium-ion battery prices, using energy storage to stretch electricity generation capacity.

Based on our research on energy storage costs and performance in North Carolina, and our analysis of the potential role energy storage could play within the coming years, we believe that utilities should prepare for the advent of cheap grid-scale batteries and develop flexible, long-term plans that will save consumers money.

All of the new utility-scale electricity capacity coming online in the U.S. in 2019 will be generated through natural gas, wind and solar power as coal, nuclear and some gas plants close. U.S. Energy Information Administration

Peak demand is pricey

The amount of electricity consumers use varies according to the time of day and between weekdays and weekends, as well as seasonally and annually as everyone goes about their business.

Those variations can be huge.

For example, the times when consumers use the most electricity in many regions is nearly double the average amount of power they typically consume. Utilities often meet peak demand by building power plants that run on natural gas, due to their lower construction costs and ability to operate when they are needed.

However, it’s expensive and inefficient to build these power plants just to meet demand in those peak hours. It’s like purchasing a large van that you will only use for the three days a year when your brother and his three kids visit.

The grid requires power supplied right when it is needed, and usage varies considerably throughout the day. When grid-connected batteries help supply enough electricity to meet demand, utilities don’t have to build as many power plants and transmission lines.

Given how long this infrastructure lasts and how rapidly battery costs are dropping, utilities now face new long-term planning challenges.

Grid-scale batteries are being installed coast-to-coast as this snapshot from 2017 indicates. Source: U.S. Energy Information Administration, U.S. Battery Storage Market Trends, 2018.

Cheaper batteries

About half of the new generation capacity built in the U.S. annually since 2014 has come from solar, wind or other renewable sources. Natural gas plants make up the much of the rest but in the future, that industry may need to compete with energy storage for market share.

In practice, we can see how the pace of natural gas-fired power plant construction might slow down in response to this new alternative.

So far, utilities have only installed the equivalent of one or two traditional power plants in grid-scale lithium-ion battery projects, all since 2015. But across California, Texas, the Midwest and New England, these devices are benefiting the overall grid by improving operations and bridging gaps when consumers need more power than usual.

Based on our own experience tracking lithium-ion battery costs, we see the potential for these batteries to be deployed at a far larger scale and disrupt the energy business.

When we were given approximately one year to conduct a study on the benefits and costs of energy storage in North Carolina, keeping up with the pace of technological advances and increasing affordability was a struggle.

Projected battery costs changed so significantly from the beginning to the end of our project that we found ourselves rushing at the end to update our analysis.

Once utilities can easily take advantage of these huge batteries, they will not need as much new power-generation capacity to meet peak demand.

What energy-storage batteries cost

Grid-scale lithium-ion battery costs per kilowatt hour have plummeted in the past four years. They will probably fall further.

Utility planning

Even before batteries could be used for large-scale energy storage, it was hard for utilities to make long-term plans due to uncertainty about what to expect in the future.

For example, most energy experts did not anticipate the dramatic decline in natural gas prices due to the spread of hydraulic fracturing, or fracking, starting about a decade ago – or the incentive that it would provide utilities to phase out coal-fired power plants.

In recent years, solar energy and wind power costs have dropped far faster than expected, also displacing coal – and in some cases natural gas – as a source of energy for electricity generation.

Something we learned during our storage study is illustrative.

We found that lithium ion batteries at 2019 prices were a bit too expensive in North Carolina to compete with natural gas peaker plants – the natural gas plants used occasionally when electricity demand spikes. However, when we modeled projected 2030 battery prices, energy storage proved to be the more cost-effective option.

Federal, state and even some local policies are another wild card. For example, Democratic lawmakers have outlined the Green New Deal, an ambitious plan that could rapidly address climate change and income inequality at the same time.

And no matter what happens in Congress, the increasingly frequent bouts of extreme weather hitting the U.S. are also expensive for utilities. Droughts reduce hydropower output and heatwaves make electricity usage spike.

The Scattergood power plant in Los Angeles is one of three natural gas power plants slated to shut down by 2029. AP Photo/Marcio Jose Sanchez

The future

Several utilities are already investing in energy storage.

California utility Pacific Gas & Electric, for example, got permission from regulators to build a massive 567.5 megawatt energy-storage battery system near San Francisco, although the utility’s bankruptcy could complicate the project.

Hawaiian Electric Company is seeking approval for projects that would establish several hundred megawatts of energy storage across the islands. And Arizona Public Service and Puerto Rico Electric Power Authority are looking into storage options as well.

We believe these and other decisions will reverberate for decades to come. If utilities miscalculate and spend billions on power plants it turns out they won’t need instead of investing in energy storage, their customers could pay more than they should to keep the lights through the middle of this century.

See the full article here .

five-ways-keep-your-child-safe-school-shootings

Please help promote STEM in your local schools.

Stem Education Coalition

The Conversation launched as a pilot project in October 2014. It is an independent source of news and views from the academic and research community, delivered direct to the public.
Our team of professional editors work with university and research institute experts to unlock their knowledge for use by the wider public.
Access to independent, high quality, authenticated, explanatory journalism underpins a functioning democracy. Our aim is to promote better understanding of current affairs and complex issues. And hopefully allow for a better quality of public discourse and conversation.

From Horizon The EU Research and Innovation Magazine: “Record-breaking solar cells get ready for mass production”

From Horizon The EU Research and Innovation Magazine

21 November 2018
Benedict O’Donnell

Researchers in Europe are trying to work out how record-breaking solar cells contacts can be mass-produced. BedZed Eco village. Image credit: Flickr- Bioregional International, licensed under CC.

Sandwiching an oxygen-rich layer of silicon between a solar cell and its metal contact has allowed researchers in Europe to break performance records for the efficiency with which silicon solar cells convert sunlight into electricity. But the challenge now is how to make these so-called passivating contacts suitable for mass production.

‘There is currently a lot of excitement about passivating contacts among the solar cell community,’ said Dr Byungsul Min at the Institute for Solar Energy Research in Hamelin (ISFH), Germany. This year, the technology allowed his laboratory to set a new record efficiency of 26.1% for the kind of solar cells the kind that dominates the photovoltaics market. Commercial solar panels currently operate with an efficiency of around 20%.

Passivating contacts consist of two thin layers of oxidised and crystallised silicon sandwiched between a solar cell and its metal contact. Speaking to a packed hall this September at the European Photovoltaics Solar Energy Conference in Brussels, Belgium, Dr Min said that the layers work by healing broken atomic bonds on the silicon surface and reducing the risk of electric charges getting trapped as they flow out of the solar cell.

The design was developed in 2013 by ISFH and the Fraunhofer Institute for Solar Energy Systems ISE in Freiburg, Germany. In recent years, it has driven the energy conversion efficiency of silicon photovoltaics above 25% – a ceiling that had limited the efficiency that researchers could achieve in the lab for over a decade.

Mass fabrication

Still, Dr Min says that few manufacturers have so far adopted passivating contacts in industry. As part of a project called DISC, he is now coordinating work with research institutes and equipment manufacturers across Europe to streamline their design for mass fabrication.

Making record-setting solar cells with passivating contacts has so far required costly materials and complex laboratory techniques that Dr Min says cannot be adopted in factory assembly lines. However, by getting rid of these sophisticated approaches and substituting them with tools that are already common in the solar cell industry, the DISC consortium expects to bring down manufacturing costs for the technology.

ISFH has notably replaced an expensive and highly conductive indium-containing layer that is deposited on the cell surface to better collect electrical charges out of the passivating contact. By fine-tuning pressure and temperature conditions during production, Dr Min can now form a zinc-containing layer that presents comparable physical properties while using abundant materials.

Dutch equipment provider Meco is swapping complex lithography steps with plating techniques that can metallise the electrical contacts of passivating contact solar cells in throughputs high enough for factory assembly lines.

Over the past year, DISC samples have shuttled across France, Germany, Switzerland and the Netherlands as partners play their part in an international supply line. Each laboratory adds a layer of silicon or other materials in which it specialises, gradually building up the stack of semiconductors into a functioning solar cell.

‘This August, we completed our first industry-sized solar cells,’ said Dr Min. ‘They have already reached energy conversion efficiencies above 21%.’ This falls within the range of solar cells on the market today.

Over the coming year, Dr Min expects that fine-tuning the layers in these factory-friendly devices will help edge their performance above that of the competition. In an industry where a difference of just half a percentage can make or break companies, a technology with a proven potential of over 25% efficiency in the laboratory offers enticing prospects for manufacturers.

‘We have to go to higher solar cell efficiencies,’ agreed Dr Martin Hermle, one of the pioneers of passivating contacts at Fraunhofer ISE. His research group is now developing industrial deposition methods for the solar cells produced in DISC, and developing ways of further boosting their energy conversion efficiency in another project called Nano-Tandem.

‘The cost of solar panels is largely dictated by their surface area. If you can make cells with 30% efficiency instead of 20% or 15%, that really helps reduce the overall cost of solar energy.’

Technology developed by two German institutes set a new record efficiency for solar cells of 26.1%. Image credit: Institute for Solar Energy Research in Hamelin.

33% efficiency

Earlier this year, Fraunhofer ISE produced a solar cell that reached a staggering 33% efficiency. Researchers stacked a silicon solar cell that incorporated passivating contacts with two additional solar cells made of more exotic materials, based on elements in the third and fifth group of the periodic table.

‘These top cells are good at absorbing blue shades of light, but they are made of comparatively rare elements, like gallium or indium, that are also slower to assemble than conventional silicon solar cells,’ said Dr Hermle. ‘If you want to compete on the mass market, you have to bring the cost of the material deposition down by about two orders of magnitude.’

One solution Nano-Tandem is exploring is to use less of them. Fraunhofer ISE has shipped silicon solar cells with passivating contacts to IBM Research Zürich, where project partners are placing solar cells on top of them not as solid layers, but as carpets of wires barely 1000 atoms wide. Startup Sol Voltaics and Lund University in Sweden are developing a potentially cheaper way of manufacturing the nanowires, assembling them from gas molecules as they fly through a tube furnace.

Nano-Tandem coordinator Professor Lars Samuelson at Lund University says that the raw materials used are expensive, but that photonic effects in them could turn their economics around. He says that, assembled wisely, manufacturers could in principle use 90% less material without much impact on the efficiency or light absorption of their solar cells.

This is the kind of innovative edge that Dr Hermle describes as crucial in keeping European research institutes at the head of solar cell technology. As the market for solar cells skyrockets into 11-digit annual figures, Asian competition is increasingly muscling European manufacturers out of business.

Dr Hermle says that passivating contacts offer an example of how European industry can remain relevant in the face of global competition. ‘This is a technology that really came from Europe to the solar cell market,’ he said.

The research in this article was funded by the EU. If you liked this article, please consider sharing it on social media.

See the full article here .

five-ways-keep-your-child-safe-school-shootings
Please help promote STEM in your local schools.

Stem Education Coalition

From Stanford University: “Stanford researchers develop a rooftop device that can make solar power and cool buildings”

From Stanford University

November 8, 2018
Tom Abate, Stanford Engineering
(650) 736-2245,
tabate@stanford.edu

Professor Shanhui Fan and postdoctoral scholar Wei Li atop the Packard Electrical Engineering building with the apparatus that is proving the efficacy of a double-layered solar panel. The top layer uses the standard semiconductor materials that go into energy-harvesting solar cells; the novel materials on the bottom layer perform the cooling task. (Image credit: L.A. Cicero)

Stanford electrical engineer Shanhui Fan wants to revolutionize energy-producing rooftop arrays.

Today, such arrays do one thing – they turn sunlight into electricity. But Fan’s lab has built a device that could have a dual purpose – generating electricity and cooling buildings.

“We’ve built the first device that one day could make energy and save energy, in the same place and at the same time, by controlling two very different properties of light,” said Fan, senior author of an article appearing Nov. 8 in Joule.

The sun-facing layer of the device is nothing new. It’s made of the same semiconductor materials that have long adorned rooftops to convert visible light into electricity. The novelty lies in the device’s bottom layer, which is based on materials that can beam heat away from the roof and into space through a process known as radiative cooling.

In radiative cooling, objects – including our own bodies – shed heat by radiating infrared light. That’s the invisible light night-vision goggles detect. Normally this form of cooling doesn’t work well for something like a building because Earth’s atmosphere acts like a thick blanket and traps the majority of the heat near the building rather allowing it to escape, ultimately into the vast coldness of space.

Holes in the blanket

Fan’s cooling technology takes advantage of the fact that this thick atmospheric blanket essentially has holes in it that allow a particular wavelength of infrared light to pass directly into space. In previous work, Fan had developed materials that can convert heat radiating off a building into the particular infrared wavelength that can pass directly through the atmosphere. These materials release heat into space and could save energy that would have been needed to air-condition a building’s interior. That same material is what Fan placed under the standard solar layer in his new device.

Zhen Chen, who led the experiments as a postdoctoral scholar in Fan’s lab, said the researchers built a prototype about the diameter of a pie plate and mounted their device on the rooftop of a Stanford building. Then they compared the temperature of the ambient air on the rooftop with the temperatures of the top and bottom layers of the device. The top layer device was hotter than the rooftop air, which made sense because it was absorbing sunlight. But, as the researchers hoped, the bottom layer of the device was significant cooler than the air on the rooftop.

“This shows that heat radiated up from the bottom, through the top layer and into space,” said Chen, who is now a professor at the Southeast University of China.

What they weren’t able to test is whether the device also produced electricity. The upper layer in this experiment lacked the metal foil, normally found in solar cells, that would have blocked the infrared light from escaping. The team is now designing solar cells that work without metal liners to couple with the radiative cooling layer.

“We think we can build a practical device that does both things,” Fan said.

Shanhui Fan is the director of the Edward L. Ginzton Laboratory, a professor of electrical engineering, a senior fellow at the Precourt Institute for Energy and a professor, by courtesy, of applied physics. Postdoctoral scholars Wei Li of Stanford and Linxiao Zhu of the University of Michigan, Ann Arbor, also co-authored the paper.

The research was supported by the Stanford University Global Climate and Energy Project, the National Science Foundation and the National Natural Science Foundation of China.

See the full article here .

five-ways-keep-your-child-safe-school-shootings
Please help promote STEM in your local schools.

Stem Education Coalition

Stanford University campus. No image credit

Stanford University

Leland and Jane Stanford founded the University to “promote the public welfare by exercising an influence on behalf of humanity and civilization.” Stanford opened its doors in 1891, and more than a century later, it remains dedicated to finding solutions to the great challenges of the day and to preparing our students for leadership in today’s complex world. Stanford, is an American private research university located in Stanford, California on an 8,180-acre (3,310 ha) campus near Palo Alto. Since 1952, more than 54 Stanford faculty, staff, and alumni have won the Nobel Prize, including 19 current faculty members

From SLAC National Accelerator Lab: “Researchers create most complete high-res atomic movie of photosynthesis to date”

From SLAC National Accelerator Lab

November 7, 2018

Andrew Gordon
agordon@slac.stanford.edu
(650) 926-2282

In a major step forward, SLAC’s X-ray laser captures all four stable states of the process that produces the oxygen we breathe, as well as fleeting steps in between. The work opens doors to understanding the past and creating a greener future.

Using SLAC’s X-ray laser, researchers have captured the most complete high-res atomic movie to date of Photosystem II, a key protein complex in plants, algae and cyanobacteria responsible for splitting water and producing the oxygen we breathe. (Gregory Stewart, SLAC National Accelerator Laboratory)

Despite its role in shaping life as we know it, many aspects of photosynthesis remain a mystery. An international collaboration between scientists at SLAC National Accelerator Laboratory, Lawrence Berkeley National Laboratory and several other institutions is working to change that. The researchers used SLAC’s Linac Coherent Light Source (LCLS) X-ray laser to capture the most complete and highest-resolution picture to date of Photosystem II, a key protein complex in plants, algae and cyanobacteria responsible for splitting water and producing the oxygen we breathe. The results were published in Nature today.

SLAC/LCLS

Explosion of life

When Earth formed about 4.5 billion years ago, the planet’s landscape was almost nothing like what it is today. Junko Yano, one of the authors of the study and a senior scientist at Berkeley Lab, describes it as “hellish.” Meteors sizzled through a carbon dioxide-rich atmosphere and volcanoes flooded the surface with magmatic seas.

Over the next 2.5 billion years, water vapor accumulating in the air started to rain down and form oceans where the very first life appeared in the form of single-celled organisms. But it wasn’t until one of those specks of life mutated and developed the ability to harness light from the sun and turn it into energy, releasing oxygen molecules from water in the process, that Earth started to evolve into the planet it is today. This process, oxygenic photosynthesis, is considered one of nature’s crown jewels and has remained relatively unchanged in the more than 2 billion years since it emerged.

“This one reaction made us as we are, as the world. Molecule by molecule, the planet was slowly enriched until, about 540 million years ago, it exploded with life,” said co-author Uwe Bergmann, a distinguished staff scientist at SLAC. “When it comes to questions about where we come from, this is one of the biggest.”

A greener future

Photosystem II is the workhorse responsible for using sunlight to break water down into its atomic components, unlocking hydrogen and oxygen. Until recently, it had only been possible to measure pieces of this process at extremely low temperatures. In a previous paper, the researchers used a new method to observe two steps of this water-splitting cycle [Nature]at the temperature at which it occurs in nature.

Now the team has imaged all four intermediate states of the process at natural temperature and the finest level of detail yet. They also captured, for the first time, transitional moments between two of the states, giving them a sequence of six images of the process.

The goal of the project, said co-author Jan Kern, a scientist at Berkeley Lab, is to piece together an atomic movie using many frames from the entire process, including the elusive transient state at the end that bonds oxygen atoms from two water molecules to produce oxygen molecules.

“Studying this system gives us an opportunity to see how metals and proteins work together and how light controls such kinds of reactions,” said Vittal Yachandra, one of the authors of the study and a senior scientist at Berkeley Lab who has been working on Photosystem II for more than 35 years. “In addition to opening a window on the past, a better understanding of Photosystem II could unlock the door to a greener future, providing us with inspiration for artificial photosynthetic systems that produce clean and renewable energy from sunlight and water.”

Sample assembly line

For their experiments, the researchers grow what Kern described as a “thick green slush” of cyanobacteria — the very same ancient organisms that first developed the ability to photosynthesize — in a large vat that is constantly illuminated. They then harvest the cells for their samples.

At LCLS, the samples are zapped with ultrafast pulses of X-rays [Science] to collect both X-ray crystallography and spectroscopy data to map how electrons flow in the oxygen-evolving complex of photosystem II. In crystallography, researchers use the way a crystal sample scatters X-rays to map its structure; in spectroscopy, they excite the atoms in a material to uncover information about its chemistry. This approach, combined with a new assembly-line sample transportation system [Nature Methods], allowed the researchers to narrow down the proposed mechanisms put forward by the research community over the years.

Mapping the process

Previously, the researchers were able to determine the room-temperature structure of two of the states at a resolution of 2.25 angstroms; one angstrom is about the diameter of a hydrogen atom. This allowed them to see the position of the heavy metal atoms, but left some questions about the exact positions of the lighter atoms, like oxygen. In this paper, they were able to improve the resolution even further, to 2 angstroms, which enabled them to start seeing the position of lighter atoms more clearly, as well as draw a more detailed map of the chemical structure of the metal catalytic center in the complex where water is split.

This center, called the oxygen-evolving complex, is a cluster of four manganese atoms and one calcium atom bridged with oxygen atoms. It cycles through the four stable oxidation states, S0-S3, when exposed to sunlight. On a baseball field, S0 would be the start of the game when a player on home base is ready to go to bat. S1-S3 would be players on first, second, and third. Every time a batter connects with a ball, or the complex absorbs a photon of sunlight, the player on the field advances one base. When the fourth ball is hit, the player slides into home, scoring a run or, in the case of Photosystem II, releasing breathable oxygen.

The researchers were able to snap action shots of how the structure of the complex transformed at every base, which would not have been possible without their technique. A second set of data allowed them to map the exact position of the system in each image, confirming that they had in fact imaged the states they were aiming for.

In photosystem II, the water-splitting center cycles through four stable states, S0-S3. On a baseball field, S0 would be the start of the game when a batter on home base is ready to hit. S1-S3 would be players waiting on first, second, and third. The center gets bumped up to the next state every time it absorbs a photon of sunlight, just like how a player on the field advances one base every time a batter connects with a ball. When the fourth ball is hit, the player slides into home, scoring a run or, in the case of Photosystem II, releasing the oxygen we breathe. (Gregory Stewart/SLAC National Accelerator Laboratory)

Sliding into home

But there are many other things going on throughout this process, as well as moments between states when the player is making a break for the next base, that are a bit harder to catch. One of the most significant aspects of this paper, Yano said, is that they were able to image two moments in between S2 and S3. In upcoming experiments, the researchers hope to use the same technique to image more of these in-between states, including the mad dash for home — the transient state, or S4, where two atoms of oxygen bond together — providing information about the chemistry of the reaction that is vital to mimicking this process in artificial systems.

“The entire cycle takes nearly two milliseconds to complete,” Kern said. “Our dream is to capture 50-microsecond steps throughout the full cycle, each of them with the highest resolution possible, to create this atomic movie of the entire process.”

Although they still have a way to go, the researchers said that these results provide a path forward, both in unveiling the mysteries of how photosynthesis works and in offering a blueprint for artificial sources of renewable energy.

“It’s been a learning process,” said SLAC scientist and co-author Roberto Alonso-Mori. “Over the last seven years we’ve worked with our collaborators to reinvent key aspects of our techniques. We’ve been slowly chipping away at this question and these results are a big step forward.”

In addition to SLAC and Berkeley Lab, the collaboration includes researchers from Umeå University, Uppsala University, Humboldt University of Berlin, the University of California, Berkeley, the University of California, San Francisco and the Diamond Light Source.

Key components of this work were carried out at SLAC’s Stanford Synchrotron Radiation Lightsource (SSRL), Berkeley Lab’s Advanced Light Source (ALS) and Argonne National Laboratory’s Advanced Photon Source (APS). LCLS, SSRL, APS, and ALS are DOE Office of Science user facilities. This work was supported by the DOE Office of Science and the National Institutes of Health, among other funding agencies.

SLAC/SSRL

LBNL/ALS

ANL APS

See the full article here .

five-ways-keep-your-child-safe-school-shootings
Please help promote STEM in your local schools.

Stem Education Coalition

SLAC is a multi-program laboratory exploring frontier questions in photon science, astrophysics, particle physics and accelerator research. Located in Menlo Park, California, SLAC is operated by Stanford University for the DOE’s Office of Science.

From MIT News: “New battery gobbles up carbon dioxide”

From MIT News

September 21, 2018
David L. Chandler

This scanning electron microscope image shows the carbon cathode of a carbon-dioxide-based battery made by MIT researchers, after the battery was discharged. It shows the buildup of carbon compounds on the surface, composed of carbonate material that could be derived from power plant emissions, compared to the original pristine surface (inset). Courtesy of the researchers

Scanning transmission electron microscope Wikipedia

Lithium-based battery could make use of greenhouse gas before it ever gets into the atmosphere.

A new type of battery developed by researchers at MIT could be made partly from carbon dioxide captured from power plants. Rather than attempting to convert carbon dioxide to specialized chemicals using metal catalysts, which is currently highly challenging, this battery could continuously convert carbon dioxide into a solid mineral carbonate as it discharges.

While still based on early-stage research and far from commercial deployment, the new battery formulation could open up new avenues for tailoring electrochemical carbon dioxide conversion reactions, which may ultimately help reduce the emission of the greenhouse gas to the atmosphere.

The battery is made from lithium metal, carbon, and an electrolyte that the researchers designed. The findings are described today in the journal Joule, in a paper by assistant professor of mechanical engineering Betar Gallant, doctoral student Aliza Khurram, and postdoc Mingfu He.

Currently, power plants equipped with carbon capture systems generally use up to 30 percent of the electricity they generate just to power the capture, release, and storage of carbon dioxide. Anything that can reduce the cost of that capture process, or that can result in an end product that has value, could significantly change the economics of such systems, the researchers say.

However, “carbon dioxide is not very reactive,” Gallant explains, so “trying to find new reaction pathways is important.” Generally, the only way to get carbon dioxide to exhibit significant activity under electrochemical conditions is with large energy inputs in the form of high voltages, which can be an expensive and inefficient process. Ideally, the gas would undergo reactions that produce something worthwhile, such as a useful chemical or a fuel. However, efforts at electrochemical conversion, usually conducted in water, remain hindered by high energy inputs and poor selectivity of the chemicals produced.

Gallant and her co-workers, whose expertise has to do with nonaqueous (not water-based) electrochemical reactions such as those that underlie lithium-based batteries, looked into whether carbon-dioxide-capture chemistry could be put to use to make carbon-dioxide-loaded electrolytes — one of the three essential parts of a battery — where the captured gas could then be used during the discharge of the battery to provide a power output.

This approach is different from releasing the carbon dioxide back to the gas phase for long-term storage, as is now used in carbon capture and sequestration, or CCS. That field generally looks at ways of capturing carbon dioxide from a power plant through a chemical absorption process and then either storing it in underground formations or chemically altering it into a fuel or a chemical feedstock.

Instead, this team developed a new approach that could potentially be used right in the power plant waste stream to make material for one of the main components of a battery.

While interest has grown recently in the development of lithium-carbon-dioxide batteries, which use the gas as a reactant during discharge, the low reactivity of carbon dioxide has typically required the use of metal catalysts. Not only are these expensive, but their function remains poorly understood, and reactions are difficult to control.

By incorporating the gas in a liquid state, however, Gallant and her co-workers found a way to achieve electrochemical carbon dioxide conversion using only a carbon electrode. The key is to preactivate the carbon dioxide by incorporating it into an amine solution.

“What we’ve shown for the first time is that this technique activates the carbon dioxide for more facile electrochemistry,” Gallant says. “These two chemistries — aqueous amines and nonaqueous battery electrolytes — are not normally used together, but we found that their combination imparts new and interesting behaviors that can increase the discharge voltage and allow for sustained conversion of carbon dioxide.”

They showed through a series of experiments that this approach does work, and can produce a lithium-carbon dioxide battery with voltage and capacity that are competitive with that of state-of-the-art lithium-gas batteries. Moreover, the amine acts as a molecular promoter that is not consumed in the reaction.

The key was developing the right electrolyte system, Khurram explains. In this initial proof-of-concept study, they decided to use a nonaqueous electrolyte because it would limit the available reaction pathways and therefore make it easier to characterize the reaction and determine its viability. The amine material they chose is currently used for CCS applications, but had not previously been applied to batteries.

This early system has not yet been optimized and will require further development, the researchers say. For one thing, the cycle life of the battery is limited to 10 charge-discharge cycles, so more research is needed to improve rechargeability and prevent degradation of the cell components. “Lithium-carbon dioxide batteries are years away” as a viable product, Gallant says, as this research covers just one of several needed advances to make them practical.

But the concept offers great potential, according to Gallant. Carbon capture is widely considered essential to meeting worldwide goals for reducing greenhouse gas emissions, but there are not yet proven, long-term ways of disposing of or using all the resulting carbon dioxide. Underground geological disposal is still the leading contender, but this approach remains somewhat unproven and may be limited in how much it can accommodate. It also requires extra energy for drilling and pumping.

The researchers are also investigating the possibility of developing a continuous-operation version of the process, which would use a steady stream of carbon dioxide under pressure with the amine material, rather than a preloaded supply the material, thus allowing it to deliver a steady power output as long as the battery is supplied with carbon dioxide. Ultimately, they hope to make this into an integrated system that will carry out both the capture of carbon dioxide from a power plant’s emissions stream, and its conversion into an electrochemical material that could then be used in batteries. “It’s one way to sequester it as a useful product,” Gallant says.

“It was interesting that Gallant and co-workers cleverly combined the prior knowledge from two different areas, metal-gas battery electrochemistry and carbon-dioxide capture chemistry, and succeeded in increasing both the energy density of the battery and the efficiency of the carbon-dioxide capture,” says Kisuk Kang, a professor at Seoul National University in South Korea, who was not associated with this research.

“Even though more precise understanding of the product formation from carbon dioxide may be needed in the future, this kind of interdisciplinary approach is very exciting and often offers unexpected results, as the authors elegantly demonstrated here,” Kang adds.

See the full article here .

five-ways-keep-your-child-safe-school-shootings
Please help promote STEM in your local schools.

Stem Education Coalition

The mission of MIT is to advance knowledge and educate students in science, technology, and other areas of scholarship that will best serve the nation and the world in the twenty-first century. We seek to develop in each member of the MIT community the ability and passion to work wisely, creatively, and effectively for the betterment of humankind.

From University of Cambridge: “Scientists pioneer a new way to turn sunlight into fuel”

From University of Cambridge

03 Sep 2018
No writer credit

The quest to find new ways to harness solar power has taken a step forward after researchers successfully split water into hydrogen and oxygen by altering the photosynthetic machinery in plants.

Experimental two-electrode setup showing the photoelectrochemical cell illuminated with simulated solar light. Credit: Katarzyna Sokół

Photosynthesis is the process plants use to convert sunlight into energy. Oxygen is produced as a by-product of photosynthesis when the water absorbed by plants is ‘split’. It is one of the most important reactions on the planet because it is the source of nearly all of the world’s oxygen. Hydrogen which is produced when the water is split could potentially be a green and unlimited source of renewable energy.

A new study led by academics at the University of Cambridge, used semi-artificial photosynthesis to explore new ways to produce and store solar energy. They used natural sunlight to convert water into hydrogen and oxygen using a mixture of biological components and manmade technologies.

The research could now be used to revolutionise the systems used for renewable energy production. A new paper, published in [Nature Energy], outlines how academics at the Reisner Laboratory in Cambridge’s Department of Chemistry developed their platform to achieve unassisted solar-driven water-splitting.

Their method also managed to absorb more solar light than natural photosynthesis.

Katarzyna Sokół, first author and PhD student at St John’s College, said: “Natural photosynthesis is not efficient because it has evolved merely to survive so it makes the bare minimum amount of energy needed – around 1-2 per cent of what it could potentially convert and store.”

Artificial photosynthesis has been around for decades but it has not yet been successfully used to create renewable energy because it relies on the use of catalysts, which are often expensive and toxic. This means it can’t yet be used to scale up findings to an industrial level.

The Cambridge research is part of the emerging field of semi-artificial photosynthesis which aims to overcome the limitations of fully artificial photosynthesis by using enzymes to create the desired reaction.

Sokół and the team of researchers not only improved on the amount of energy produced and stored, they managed to reactivate a process in the algae that has been dormant for millennia.

She explained: “Hydrogenase is an enzyme present in algae that is capable of reducing protons into hydrogen. During evolution, this process has been deactivated because it wasn’t necessary for survival but we successfully managed to bypass the inactivity to achieve the reaction we wanted – splitting water into hydrogen and oxygen.”

Sokół hopes the findings will enable new innovative model systems for solar energy conversion to be developed.

She added: “It’s exciting that we can selectively choose the processes we want, and achieve the reaction we want which is inaccessible in nature. This could be a great platform for developing solar technologies. The approach could be used to couple other reactions together to see what can be done, learn from these reactions and then build synthetic, more robust pieces of solar energy technology.”

This model is the first to successfully use hydrogenase and photosystem II to create semi-artificial photosynthesis driven purely by solar power.

Dr Erwin Reisner, Head of the Reisner Laboratory, a Fellow of St John’s College, University of Cambridge, and one of the paper’s authors described the research as a ‘milestone’.

He explained: “This work overcomes many difficult challenges associated with the integration of biological and organic components into inorganic materials for the assembly of semi-artificial devices and opens up a toolbox for developing future systems for solar energy conversion.”

See the full article here .

five-ways-keep-your-child-safe-school-shootings

Please help promote STEM in your local schools.

Stem Education Coalition

The University of Cambridge (abbreviated as Cantab in post-nominal letters) is a collegiate public research university in Cambridge, England. Founded in 1209, Cambridge is the second-oldest university in the English-speaking world and the world’s fourth-oldest surviving university. It grew out of an association of scholars who left the University of Oxford after a dispute with townsfolk. The two ancient universities share many common features and are often jointly referred to as “Oxbridge”.

Cambridge is formed from a variety of institutions which include 31 constituent colleges and over 100 academic departments organised into six schools. The university occupies buildings throughout the town, many of which are of historical importance. The colleges are self-governing institutions founded as integral parts of the university. In the year ended 31 July 2014, the university had a total income of £1.51 billion, of which £371 million was from research grants and contracts. The central university and colleges have a combined endowment of around £4.9 billion, the largest of any university outside the United States. Cambridge is a member of many associations and forms part of the “golden triangle” of leading English universities and Cambridge University Health Partners, an academic health science centre. The university is closely linked with the development of the high-tech business cluster known as “Silicon Fen”.

From UCLA Newsroom: “Dual-layer solar cell developed at UCLA sets record for efficiently generating power”

From UCLA Newsroom

August 30, 2018
Matthew Chin

A solar cell developed by UCLA Engineering researchers converts 22.4 percent of incoming energy from the sun, a record for this type of cell. Oszie Tarula/UCLA

Materials scientists from the UCLA Samueli School of Engineering have developed a highly efficient thin-film solar cell that generates more energy from sunlight than typical solar panels, thanks to its double-layer design.

The device is made by spraying a thin layer of perovskite — an inexpensive compound of lead and iodine that has been shown to be very efficient at capturing energy from sunlight — onto a commercially available solar cell. The solar cell that forms the bottom layer of the device is made of a compound of copper, indium, gallium and selenide, or CIGS.

The team’s new cell converts 22.4 percent of the incoming energy from the sun, a record in power conversion efficiency for a perovskite–CIGS tandem solar cell. The performance was confirmed in independent tests at the U.S. Department of Energy’s National Renewable Energy Laboratory. (The previous record, set in 2015 by a group at IBM’s Thomas J. Watson Research Center, was 10.9 percent.) The UCLA device’s efficiency rate is similar to that of the poly-silicon solar cells that currently dominate the photovoltaics market.

The research, which was published today in Science, was led by Yang Yang, UCLA’s Carol and Lawrence E. Tannas Jr. Professor of Materials Science.

Qifeng Han, Yang Yang and Lei Meng. Oszie Tarula/UCLA

“With our tandem solar cell design, we’re drawing energy from two distinct parts of the solar spectrum over the same device area,” Yang said. “This increases the amount of energy generated from sunlight compared to the CIGS layer alone.”

Yang added that the technique of spraying on a layer of perovskite could be easily and inexpensively incorporated into existing solar-cell manufacturing processes.

The cell’s CIGS base layer, which is about 2 microns (or two-thousandths of a millimeter) thick, absorbs sunlight and generates energy at a rate of 18.7 percent efficiency on its own, but adding the 1 micron-thick perovskite layer improves its efficiency — much like how adding a turbocharger to a car engine can improve its performance. The two layers are joined by a nanoscale interface that the UCLA researchers designed; the interface helps give the device higher voltage, which increases the amount of power it can export.

And the entire assembly sits on a glass substrate that’s about 2 millimeters thick.

“Our technology boosted the existing CIGS solar cell performance by nearly 20 percent from its original performance,” Yang said. “That means a 20 percent reduction in energy costs.”

He added that devices using the two-layer design could eventually approach 30 percent power conversion efficiency. That will be the research group’s next goal.

The study’s lead authors are Qifeng Han, a visiting research associate in Yang’s laboratory, and Yao-Tsung Hsieh and Lei Meng, who both recently earned their doctorates at UCLA. The study’s other authors are members of Yang’s research group and researchers from Solar Frontier Corp.’s Atsugi Research Center in Japan.

The research was supported by the National Science Foundation and the Air Force Office of Scientific Research. Yang and his research group have been working on tandem solar cells for several years and their accomplishments include developing transparent tandem solar cells that could be used in windows.

See the full article here .

five-ways-keep-your-child-safe-school-shootings
Please help promote STEM in your local schools.

Stem Education Coalition

For nearly 100 years, UCLA has been a pioneer, persevering through impossibility, turning the futile into the attainable.

We doubt the critics, reject the status quo and see opportunity in dissatisfaction. Our campus, faculty and students are driven by optimism. It is not naïve; it is essential. And it has fueled every accomplishment, allowing us to redefine what’s possible, time after time.

This can-do perspective has brought us 12 Nobel Prizes, 12 Rhodes Scholarships, more NCAA titles than any university and more Olympic medals than most nations. Our faculty and alumni helped create the Internet and pioneered reverse osmosis. And more than 100 companies have been created based on technology developed at UCLA.

From CSIROscope: “How hydrogen power can help us cut emissions, boost exports, and even drive further between refills”

From CSIROscope

24 August 2018
Sam Bruce

Could this be the way to fill up in future?

Hydrogen could become a significant part of Australia’s energy landscape within the coming decade, competing with both natural gas and batteries, according to our new roadmap for the industry.

Hydrogen gas is a versatile energy carrier with a wide range of potential uses. However, hydrogen is not freely available in the atmosphere as a gas. It therefore requires an energy input and a series of technologies to produce, store and then use it.

Why would we bother? Because hydrogen has several advantages over other energy carriers, such as batteries. It is a single product that can service multiple markets and, if produced using low- or zero-emissions energy sources, it can help us significantly cut greenhouse emissions.

Potential uses for hydrogen. No image credit.

Compared with batteries, hydrogen can release more energy per unit of mass. This means that in contrast to electric battery-powered cars, it can allow passenger vehicles to cover longer distances without refuelling. Refuelling is quicker too and is likely to stay that way.

The benefits are potentially even greater for heavy vehicles such as buses and trucks which already carry heavy payloads, and where lengthy battery recharge times can affect the business model.

Hydrogen can also play an important role in energy storage, which will be increasingly necessary both in remote operations such as mine sites, and as part of the electricity grid to help smooth out the contribution of renewables such as wind and solar. This could work by using the excess renewable energy (when generation is high and/or demand is low) to drive hydrogen production via electrolysis of water. The hydrogen can then be stored as compressed gas and put into a fuel cell to generate electricity when needed.

Australia is heavily reliant on imported liquid fuels and does not currently have enough liquid fuel held in reserve. Moving towards hydrogen fuel could potentially alleviate this problem. Hydrogen can also be used to produce industrial chemicals such as ammonia and methanol, and is an important ingredient in petroleum refining.

Further, as hydrogen burns without greenhouse emissions, it is one of the few viable green alternatives to natural gas for generating heat.

Our roadmap predicts that the global market for hydrogen will grow in the coming decades. Among the prospective buyers of Australian hydrogen would be Japan, which is comparatively constrained in its ability to generate energy locally. Australia’s extensive natural resources, namely solar, wind, fossil fuels and available land lend favourably to the establishment of hydrogen export supply chains.

Why embrace hydrogen now?

Given its widespread use and benefit, interest in the “hydrogen economy” has peaked and troughed for the past few decades. Why might it be different this time around? While the main motivation is hydrogen’s ability to deliver low-carbon energy, there are a couple of other factors that distinguish today’s situation from previous years.

Our analysis shows that the hydrogen value chain is now underpinned by a series of mature technologies that are technically ready but not yet commercially viable. This means that the narrative around hydrogen has now shifted from one of technology development to “market activation”.

The solar panel industry provides a recent precedent for this kind of burgeoning energy industry. Large-scale solar farms are now generating attractive returns on investment, without any assistance from government. One of the main factors that enabled solar power to reach this tipping point was the increase in production economies of scale, particularly in China. Notably, China has recently emerged as a proponent for hydrogen, earmarking its use in both transport and distributed electricity generation.

But whereas solar power could feed into a market with ready-made infrastructure (the electricity grid), the case is less straightforward for hydrogen. The technologies to help produce and distribute hydrogen will need to develop in concert with the applications themselves.

A roadmap for hydrogen

In light of this, the primary objective of our National Hydrogen Roadmap is to provide a blueprint for the development of a hydrogen industry in Australia. With several activities already underway, it is designed to help industry, government and researchers decide where exactly to focus their attention and investment.

Our first step was to calculate the price points at which hydrogen can compete commercially with other technologies. We then worked backwards along the value chain to understand the key areas of investment needed for hydrogen to achieve competitiveness in each of the identified potential markets. Following this, we modelled the cumulative impact of the investment priorities that would be feasible in or around 2025.

What became evident from the report was that the opportunity for clean hydrogen to compete favourably on a cost basis with existing industrial feedstocks and energy carriers in local applications such as transport and remote area power systems is within reach. On the upstream side, some of the most material drivers of reductions in cost include the availability of cheap low emissions electricity, utilisation and size of the asset.

The development of an export industry, meanwhile, is a potential game-changer for hydrogen and the broader energy sector. While this industry is not expected to scale up until closer to 2030, this will enable the localisation of supply chains, industrialisation and even automation of technology manufacture that will contribute to significant reductions in asset capital costs. It will also enable the development of fossil-fuel-derived hydrogen with carbon capture and storage, and place downward pressure on renewable energy costs dedicated to large scale hydrogen production via electrolysis.

In light of global trends in industry, energy and transport, development of a hydrogen industry in Australia represents a real opportunity to create new growth areas in our economy. Blessed with unparalleled resources, a skilled workforce and established manufacturing base, Australia is extremely well placed to capitalise on this opportunity. But it won’t eventuate on its own.

See the full article here .

five-ways-keep-your-child-safe-school-shootings

Please help promote STEM in your local schools.

Stem Education Coalition

SKA/ASKAP radio telescope at the Murchison Radio-astronomy Observatory (MRO) in Mid West region of Western Australia

So what can we expect these new radio projects to discover? We have no idea, but history tells us that they are almost certain to deliver some major surprises.

Making these new discoveries may not be so simple. Gone are the days when astronomers could just notice something odd as they browse their tables and graphs.

Nowadays, astronomers are more likely to be distilling their answers from carefully-posed queries to databases containing petabytes of data. Human brains are just not up to the job of making unexpected discoveries in these circumstances, and instead we will need to develop “learning machines” to help us discover the unexpected.

With the right tools and careful insight, who knows what we might find.

CSIRO, the Commonwealth Scientific and Industrial Research Organisation, is Australia’s national science agency and one of the largest and most diverse research agencies in the world.