From Niels Bohr Institute: “Quantum Alchemy: Researchers use laser light to transform metal into magnet”

University of Copenhagen

Niels Bohr Institute bloc

From Niels Bohr Institute

16 September 2019

Mark Spencer Rudner
Associate Professor
Condensed Matter Physics
Niels Bohr Institutet
rudner@nbi.ku.dk

Maria Hornbek
Journalist
The Faculty of Science
maho@science.ku.dk
+45 22 95 42 83

CONDENSED MATTER PHYSICS: Pioneering physicists from the University of Copenhagen and Nanyang Technological University in Singapore have discovered a way to get non-magnetic materials to make themselves magnetic by way of laser light. The phenomenon may also be used to endow many other materials with new properties.

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Mark Rudner, Niels Bohr Institute, University of Copenhagen

2
Asst Prof Justin Song Chien Wen

The intrinsic properties of materials arise from their chemistry — from the types of atoms that are present and the way that they are arranged. These factors determine, for example, how well a material may conduct electricity or whether or not it is magnetic. Therefore, the traditional route for changing or achieving new material properties has been through chemistry.

Now, a pair of researchers from the University of Copenhagen and Nanyang Technological University in Singapore have discovered a new physical route to the transformation of material properties: when stimulated by laser light, a metal can transform itself from within and suddenly acquire new properties.

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“For several years, we have been looking into how to transform the properties of a matter by irradiating it with certain types of light. What’s new is that not only can we change the properties using light, we can trigger the material to change itself, from the inside out, and emerge into a new phase with completely new properties. For instance, a non-magnetic metal can suddenly transform into a magnet,” explains Associate Professor Mark Rudner, a researcher at the University of Copenhagen’s Niels Bohr Institute.

He and colleague Justin Song of Nanyang Technological University in Singapore made the discovery that is now published in Nature Physics. The idea of using light to transform the properties of a material is not novel in itself. But up to now, researchers have only been capable of manipulating the properties already found in a material. Giving a metal its own ‘separate life’, allowing it to generate its own new properties, has never been seen before.

By way of theoretical analysis, the researchers have succeeded in proving that when a non-magnetic metallic disk is irradiated with linearly polarized light, circulating electric currents and hence magnetism can spontaneously emerge in the disk.

Researchers use so-called plasmons (a type of electron wave) found in the material to change its intrinsic properties. When the material is irradiated with laser light, plasmons in the metal disk begin to rotate in either a clockwise or counterclockwise direction. However, these plasmons change the quantum electronic structure of a material, which simultaneously alters their own behavior, catalyzing a feedback loop. Feedback from the plasmons’ internal electric fields eventually causes the plasmons to break the intrinsic symmetry of the material and trigger an instability toward self-rotation that causes the metal to become magnetic.

Technique can produce properties ‘on demand’

According to Mark Rudner, the new theory pries open an entire new mindset and most likely, a wide range of applications:

“It is an example of how the interaction between light and material can be used to produce certain properties in a material ‘on demand’. It also paves the way for a multitude of uses, because the principle is quite general and can work on many types of materials. We have demonstrated that we can transform a material into a magnet. We might also be able to change it into a superconductor or something entirely different,” says Rudner. He adds:

“You could call it 21st century alchemy. In the Middle Ages, people were fascinated by the prospect of transforming lead into gold. Today, we aim to get one material to behave like another by stimulating it with a laser.”

Among the possibilities, Rudner suggests that the principle could be useful in situations where one needs a material to alternate between behaving magnetically and not. It could also prove useful in opto-electronics – where, for example, light and electronics are combined for fiber-internet and sensor development.

The researchers’ next steps are to expand the catalog of properties that can be altered in analogous ways, and to help stimulate their experimental investigation and utilization.

See the full article here .


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Niels Bohr Institute Campus

Niels Bohr Institute (Danish: Niels Bohr Institutet) is a research institute of the University of Copenhagen. The research of the institute spans astronomy, geophysics, nanotechnology, particle physics, quantum mechanics and biophysics.

The Institute was founded in 1921, as the Institute for Theoretical Physics of the University of Copenhagen, by the Danish theoretical physicist Niels Bohr, who had been on the staff of the University of Copenhagen since 1914, and who had been lobbying for its creation since his appointment as professor in 1916. On the 80th anniversary of Niels Bohr’s birth – October 7, 1965 – the Institute officially became The Niels Bohr Institute.[1] Much of its original funding came from the charitable foundation of the Carlsberg brewery, and later from the Rockefeller Foundation.[2]

During the 1920s, and 1930s, the Institute was the center of the developing disciplines of atomic physics and quantum physics. Physicists from across Europe (and sometimes further abroad) often visited the Institute to confer with Bohr on new theories and discoveries. The Copenhagen interpretation of quantum mechanics is named after work done at the Institute during this time.

On January 1, 1993 the institute was fused with the Astronomic Observatory, the Ørsted Laboratory and the Geophysical Institute. The new resulting institute retained the name Niels Bohr Institute.

The University of Copenhagen (UCPH) (Danish: Københavns Universitet) is the oldest university and research institution in Denmark. Founded in 1479 as a studium generale, it is the second oldest institution for higher education in Scandinavia after Uppsala University (1477). The university has 23,473 undergraduate students, 17,398 postgraduate students, 2,968 doctoral students and over 9,000 employees. The university has four campuses located in and around Copenhagen, with the headquarters located in central Copenhagen. Most courses are taught in Danish; however, many courses are also offered in English and a few in German. The university has several thousands of foreign students, about half of whom come from Nordic countries.

The university is a member of the International Alliance of Research Universities (IARU), along with University of Cambridge, Yale University, The Australian National University, and UC Berkeley, amongst others. The 2016 Academic Ranking of World Universities ranks the University of Copenhagen as the best university in Scandinavia and 30th in the world, the 2016-2017 Times Higher Education World University Rankings as 120th in the world, and the 2016-2017 QS World University Rankings as 68th in the world. The university has had 9 alumni become Nobel laureates and has produced one Turing Award recipient

#21st-century-alchemy, #applied-research-technology, #condensed-matter-physics, #laser-technology-2, #niels-bohr-institute, #plasmons

From UCLA Newsroom: “New insights about carbon and ice could clarify inner workings of Earth, other planets”


From UCLA Newsroom

Media Contact

Stuart Wolpert
UCLA
310-206-0511
swolpert@stratcomm.ucla.edu

May 22, 2019
Christopher Crockett

1
New simulations suggest that carbon (C) routinely bonded with iron (Fe), silicon (Si) and oxygen (O) deep within the magma ocean that covered Earth when it was young. Natalia Solomatova/École Normale Supérieure de Lyon.

2
ORNL super-cold states of water. phys.org

Most people behave differently when under extreme pressure. Carbon and ice are no different.

Two new studies show how these key planetary ingredients take on exotic forms that could help researchers better understand the composition of Earth’s core as well as the cores of planets across the galaxy. Craig Manning, a UCLA professor of geology and geochemistry, is a co-senior author of one of the papers, which was published today in the journal Nature, and senior author of the other, which was published in Nature Communications in February.

The Nature Communications paper revealed that high pressure deep inside the young Earth may have driven vast stores of carbon into the planet’s core while also setting the stage for diamonds to form. In the Nature report, researchers found that water ice undergoes a complex crystalline metamorphosis as the pressure slowly ratchets up.

Scientists have long understood that the amount of carbon sequestered in present-day Earth’s rocks, oceans and atmosphere is always in flux because the planet shuffles the element around in a vast cycle that helps regulate climate. But researchers don’t know whether the Earth locked away even more carbon deep in its interior during its formative years — information that could reveal a little more about how our planet and others like it are built.

To pursue an answer to that question, Manning and colleagues calculated how carbon might have interacted with other atoms under conditions similar to those that prevailed roughly 4.5 billion years ago, when much of Earth was still molten. Using supercomputers, the team created simulations to explore what would happen to carbon at temperatures above 3,000 degrees Celsius (more than 5,400 degrees Fahrenheit) and at pressures more than 100,000 times of those on Earth’s surface today.

The experiment revealed that under those conditions, carbon tends to link up with iron, which implies that there might be considerable quantities of carbon sealed in Earth’s iron core today. Researchers had already suspected that in the young planet’s magma ocean, iron atoms hooked up with one another and then dropped to the planet’s center. But the new research suggests that this molten iron rain may have also dragged carbon down with it. Until now, researchers weren’t even sure whether carbon exists down there.

The team also found that as the pressure ramps up, carbon increasingly bonds with itself, forming long chains of carbon atoms with oxygen atoms sticking out.

“These complex chains are a form of carbon bonding that we really hadn’t anticipated at these conditions,” Manning said.

Such molecules could be a precursor to diamonds, which consist of many carbon atoms linked together.

Solving an icy enigma

The machinations of carbon under pressure provide clues as to how Earth-like planets are built. Frozen planets and moons in other solar systems, however, may also have to contend with water ice. In a separate paper, Manning and another team of scientists looked at how the molecular structure of extremely cold ice changes when put under intense pressure.

Under everyday conditions, water ice is made up of molecules laid out in honeycomb-like mosaics of hexagons. But when ice is exposed to crushing pressure or very low temperature — in labs or possibly deep inside remote worlds — the molecules can assume a bewildering variety of patterns.

One of those patterns, known as amorphous ice, is an enigma. In amorphous ice, the water molecules eschew rigid crystalline order and take on a free-form arrangement. Manning and colleagues set out to try and understand how amorphous ice forms.

First, they chilled normal ice to about 170 degrees below zero Celsius (about 274 degrees below zero Fahrenheit). Then, they locked the ice in the jaws of a high-tech vice grip inside a cryogenic vacuum chamber. Finally, over the span of several hours, they slowly stepped up the pressure in the chamber to about 15,000 times atmospheric pressure. They stopped raising the pressure periodically to fire neutrons through the ice so that they could see the arrangement of the water molecules.

Surprisingly to the researchers, the amorphous ice never formed. Instead, the molecules went through a series of previously known crystalline arrangements.

However, when the researchers conducted the same experiment but raised the pressure much more rapidly — this time in just 30 minutes — amorphous ice formed as expected. The results suggest that time is the secret ingredient: When pressure increases slowly, tiny seeds of crystalline ice have time to form and take over the sample. Otherwise, those seeds never get a chance to grow.

The findings, published May 23 in the journal Nature [above], could be useful to researchers who study worlds orbiting other suns and are curious about what conditions might be like deep inside frozen planets.

“It’s entirely likely that there are planets dominated by ice in other solar systems that could obtain these pressures and temperatures with ease,” Manning said. “We have to have this right if we’re going to have a baseline for understanding the interiors of cold worlds that may not be like Earth.”

Both papers were funded in part by the Deep Carbon Observatory, a 10-year program started in 2009 to investigate the quantities, movements, forms and origins of deep carbon inside Earth. The Nature Communications paper was also funded by the European Research Council and was co-authored by researchers at the Ecole Normale Supérieure de Lyon in France, one of whom — Natalia Solomatova — completed her undergraduate studies at UCLA. The Nature paper was co-authored by UCLA geologist Adam Makhluf and researchers from Oak Ridge National Laboratory and the National Research Council of Canada.

See the full article here .
See also in phys.org here.


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UC LA Campus

For nearly 100 years, UCLA has been a pioneer, persevering through impossibility, turning the futile into the attainable.

We doubt the critics, reject the status quo and see opportunity in dissatisfaction. Our campus, faculty and students are driven by optimism. It is not naïve; it is essential. And it has fueled every accomplishment, allowing us to redefine what’s possible, time after time.

This can-do perspective has brought us 12 Nobel Prizes, 12 Rhodes Scholarships, more NCAA titles than any university and more Olympic medals than most nations. Our faculty and alumni helped create the Internet and pioneered reverse osmosis. And more than 100 companies have been created based on technology developed at UCLA.

#applied-research-technology, #basic-research, #carbon-and-ice, #chemistry, #condensed-matter-physics, #earth-observation, #most-people-behave-differently-when-under-extreme-pressure-carbon-and-ice-are-no-different, #physics, #ucla

From Brookhaven National Lab: “Putting a New Spin on Majorana Fermions”

From Brookhaven National Lab

April 1, 2019
Ariana Tantillo
atantillo@bnl.gov
(631) 344-2347

Peter Genzer
genzer@bnl.gov
(631) 344-3174

Split electrons that emerge at the boundaries between different magnetic states in materials known as spin ladders could act as stable bits of information in next-generation quantum computers.

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Theoretical calculations performed by (left to right) Neil Robinson, Robert Konik, Alexei Tsvelik, and Andreas Weichselbaum of Brookhaven Lab’s Condensed Matter Physics and Materials Science Department suggest that Majorana fermions exist in the boundaries of magnetic materials with different magnetic phases. Majorana fermions are particle-like excitations that emerge when single electrons fractionalize into two halves, and their unique properties are of interest for quantum applications.

The combination of different phases of water—solid ice, liquid water, and water vapor—would require some effort to achieve experimentally. For instance, if you wanted to place ice next to vapor, you would have to continuously chill the water to maintain the solid phase while heating it to maintain the gas phase.

For condensed matter physicists, this ability to create different conditions in the same system is desirable because interesting phenomena and properties often emerge at the interfaces between two phases. Of current interest is the conditions under which Majorana fermions might appear near these boundaries.

Majorana fermions are particle-like excitations called quasiparticles that emerge as a result of the fractionalization (splitting) of individual electrons into two halves. In other words, an electron becomes an entangled (linked) pair of two Majorana quasiparticles, with the link persisting regardless of the distance between them. Scientists hope to use Majorana fermions that are physically separated in a material to reliably store information in the form of qubits, the building blocks of quantum computers. The exotic properties of Majoranas—including their high insensitivity to electromagnetic fields and other environmental “noise”—make them ideal candidates for carrying information over long distances without loss.

However, to date, Majorana fermions have only been realized in materials at extreme conditions, including at frigid temperatures close to absolute zero (−459 degrees Fahrenheit) and under high magnetic fields. And though they are “topologically” protected from local atomic impurities, disorder, and defects that are present in all materials (i.e., their spatial properties remain the same even if the material is bent, twisted, stretched, or otherwise distorted), they do not survive under strong perturbations. In addition, the range of temperatures over which they can operate is very narrow. For these reasons, Majorana fermions are not yet ready for practical technological application.

Now, a team of physicists led by the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and including collaborators from China, Germany, and the Netherlands has proposed a novel theoretical method for producing more robust Majorana fermions. According to their calculations, as described in a paper published on Jan. 15 in Physical Review Letters, these Majoranas emerge at higher temperatures (by many orders of magnitude) and are largely unaffected by disorder and noise. Even though they are not topologically protected, they can persist if the perturbations change slowly from one point to another in space.

“Our numerical and analytical calculations provide evidence that Majorana fermions exist in the boundaries of magnetic materials with different magnetic phases, or directions of electron spins, positioned next to one other,” said co-author Alexei Tsvelik, senior scientist and leader of the Condensed Matter Theory Group in Brookhaven Lab’s Condensed Matter Physics and Materials Science (CMPMS) Department. “We also determined the number of Majorana fermions you should expect to get if you combine certain magnetic phases.”

For their theoretical study, the scientists focused on magnetic materials called spin ladders, which are crystals formed of atoms with a three-dimensional (3-D) structure subdivided into pairs of chains that look like ladders. Though the scientists have been studying the properties of spin ladder systems for many years and expected that they would produce Majorana fermions, they did not know how many. To perform their calculations, they applied the mathematical framework of quantum field theory for describing the fundamental physics of elementary particles, and a numerical method (density-matrix renormalization group) for simulating quantum systems whose electrons behave in a strongly correlated way.

“We were surprised to learn that for certain configurations of magnetic phases we can generate more than one Majorana fermion at each boundary,” said co-author and CMPMS Department Chair Robert Konik.

For Majorana fermions to be practically useful in quantum computing, they need to be generated in large numbers. Computing experts believe that the minimum threshold at which quantum computers will be able to solve problems that classical computers cannot is 100 qubits. The Majorana fermions also have to be moveable in such a way that they can become entangled.

The team plans to follow up their theoretical study with experiments using engineered systems such as quantum dots (nanosized semiconducting particles) or trapped (confined) ions. Compared to the properties of real materials, those of engineered ones can be more easily tuned and manipulated to introduce the different phase boundaries where Majorana fermions may emerge.

“What the next generation of quantum computers will be made of is unclear right now,” said Konik. “We’re trying to find better alternatives to the low-temperature superconductors of the current generation, similar to how silicon replaced germanium in transistors. We’re in such early stages that we need to explore every possibility available.”

See the full article here .


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One of ten national laboratories overseen and primarily funded by the Office of Science of the U.S. Department of Energy (DOE), Brookhaven National Laboratory conducts research in the physical, biomedical, and environmental sciences, as well as in energy technologies and national security. Brookhaven Lab also builds and operates major scientific facilities available to university, industry and government researchers. The Laboratory’s almost 3,000 scientists, engineers, and support staff are joined each year by more than 5,000 visiting researchers from around the world. Brookhaven is operated and managed for DOE’s Office of Science by Brookhaven Science Associates, a limited-liability company founded by Stony Brook University, the largest academic user of Laboratory facilities, and Battelle, a nonprofit, applied science and technology organization.
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#putting-a-new-spin-on-majorana-fermions, #applied-research-technology, #bnl, #condensed-matter-physics, #majorana-fermions-are-particle-like-excitations-called-quasiparticles-that-emerge-as-a-result-of-the-fractionalization-splitting-of-individual-electrons-into-two-halves, #material-sciences-2, #particle-physics, #physics, #quantum-computing, #spin-ladders-crystals-formed-of-atoms-with-a-three-dimensional-3-d-structure-subdivided-into-pairs-of-chains-that-look-like-ladders

From Lawrence Berkeley National Lab: “Revealing Hidden Spin: Unlocking New Paths Toward High-Temperature Superconductors”

Berkeley Logo

From Lawrence Berkeley National Lab

January 3, 2019

Theresa Duque
tnduque@lbl.gov
(510) 495-2418

Berkeley Lab researchers uncover insights into superconductivity, leading potentially to more efficient power transmission.

1
A research team led by Berkeley Lab’s Alessandra Lanzara (second from left) used a SARPES (spin- and angle-resolved photoemission spectroscopy) detector to uncover a distinct pattern of electron spins within the material. Co-lead authors are Kenneth Gotlieb (second from right) and Chiu-Yun Lin (right). The study’s co-authors include Chris Jozwiak of Berkeley Lab’s Advanced Light Source (left). (Credit: Peter DaSilva/Berkeley Lab)

In the 1980s, the discovery of high-temperature superconductors known as cuprates upended a widely held theory that superconductor materials carry electrical current without resistance only at very low temperatures of around 30 Kelvin (or minus 406 degrees Fahrenheit). For decades since, researchers have been mystified by the ability of some cuprates to superconduct at temperatures of more than 100 Kelvin (minus 280 degrees Fahrenheit).

Now, researchers at the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab) have unveiled a clue into the cuprates’ unusual properties – and the answer lies within an unexpected source: the electron spin. Their paper describing the research behind this discovery was published on Dec. 13 in the journal Science.

Adding electron spin to the equation

Every electron is like a tiny magnet that points in a certain direction. And electrons within most superconductor materials seem to follow their own inner compass. Rather than pointing in the same direction, their electron spins haphazardly point every which way – some up, some down, others left or right.

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With the spin resolution enabled by SARPES, Berkeley Lab researchers revealed magnetic properties of Bi-2212 that have gone unnoticed in previous studies. (Credit: Kenneth Gotlieb, Chiu-Yun Lin, et al./Berkeley Lab)

When scientists are developing new kinds of materials, they usually look at the materials’ electron spin, or the direction in which the electrons are pointing. But when it comes to making superconductors, condensed matter physicists haven’t traditionally focused on spin, because the conventionally held view was that all of the properties that make these materials unique were shaped only by the way in which two electrons interact with each other through what’s known as “electron correlation.”

But when a research team led by Alessandra Lanzara, a faculty scientist in Berkeley Lab’s Materials Sciences Division and a Charles Kittel Professor of Physics at UC Berkeley, used a unique detector to measure samples of an exotic cuprate superconductor, Bi-2212 (bismuth strontium calcium copper oxide), with a powerful technique called SARPES (spin- and angle-resolved photoemission spectroscopy), they uncovered something that defied everything they had ever known about superconductors: a distinct pattern of electron spins within the material.

“In other words, we discovered that there was a well-defined direction in which each electron was pointing given its momentum, a property also known as spin-momentum locking,” said Lanzara. “Finding it in high-temperature superconductors was a big surprise.”

A new map for high-temperature superconductors

In the world of superconductors, “high temperature” means that the material can conduct electricity without resistance at temperatures higher than expected but still in extremely cold temperatures far below zero degrees Fahrenheit. That’s because superconductors need to be extraordinarily cold to carry electricity without any resistance. At those low temperatures, electrons are able to move in sync with each other and not get knocked by jiggling atoms, causing electrical resistance.

And within this special class of high-temperature superconductor materials, cuprates are some of the best performers, leading some researchers to believe that they have potential use as a new material for building super-efficient electrical wires that can carry power without any loss of electron momentum, said co-lead author Kenneth Gotlieb, who was a Ph.D. student in Lanzara’s lab at the time of the discovery. Understanding what makes some exotic cuprate superconductors such as Bi-2212 work at temperatures as high as 133 Kelvin (about -220 degrees Fahrenheit) could make it easier to realize a practical device.

Among the very exotic materials that condensed matter physicists study, there are two kinds of electron interactions that give rise to novel properties for new materials, including superconductors, said Gotlieb. Scientists who have been studying cuprate superconductors have focused on just one of those interactions: electron correlation.

The other kind of electron interaction found in exotic materials is “spin-orbit coupling” – the way in which the electron’s magnetic moment interacts with atoms in the material.

Spin-orbit coupling was often neglected in the studies of cuprate superconductors, because many assumed that this kind of electron interaction would be weak when compared to electron correlation, said co-lead author Chiu-Yun Lin, a researcher in the Lab’s Materials Sciences Division and a Ph.D. student in the Department of Physics at UC Berkeley. So when they found the unusual spin pattern, Lin said that although they were pleasantly surprised by this initial finding, they still weren’t sure whether it was a “true” intrinsic property of the Bi-2212 material, or an external effect caused by the way the laser light interacted with the material in the experiment.

Shining a light on electron spin with SARPES

Over the course of nearly three years, Gotlieb and Lin used the SARPES detector to thoroughly map out the spin pattern at Lanzara’s lab. When they needed higher photon energies to excite a wider range of electrons within a sample, the researchers moved the detector next door to Berkeley Lab’s synchrotron, the Advanced Light Source (ALS), a U.S. DOE Office of Science User Facility that specializes in lower energy, “soft” X-ray light for studying the properties of materials.

LBNL/ALS

The SARPES detector was developed by Lanzara, along with co-authors Zahid Hussain, the former ALS Division Deputy, and Chris Jozwiak, an ALS staff scientist. The detector allowed the scientists to probe key electronic properties of the electrons such as valence band structure.

After tens of experiments at the ALS, where the team of researchers connected the SARPES detector to Beamline 10.0.1 so they could access this powerful light to explore the spin of the electrons moving with much higher momentum through the superconductor than those they could access in the lab, they found that Bi-2212’s distinct spin pattern – called “nonzero spin – was a true result, inspiring them to ask even more questions. “There remains many unsolved questions in the field of high-temperature superconductivity,” said Lin. “Our work provides new knowledge to better understand the cuprate superconductors, which can be a building block to resolve these questions.”

Lanzara added that their discovery couldn’t have happened without the collaborative “team science” of Berkeley Lab, a DOE national lab with historic ties to nearby UC Berkeley. “This work is a typical example of where science can go when people with expertise across the scientific disciplines come together, and how new instrumentation can push the boundaries of science,” she said.

Co-authors with Gotlieb, Lin, and Lanzara are Maksym Serbyn of the Institute of Science and Technology Austria, Wentao Zhang of Shanghai Jiao Tong University, Christopher L. Smallwood of San Jose State University, Christopher Jozwiak of Berkeley Lab, Hiroshi Eisaki of the National Institute of Advanced Industrial Science and Technology of Japan, Zahid Hussain of Berkeley Lab, and Ashvin Vishwanath, formerly of UC Berkeley and now with Harvard University and a Faculty Scientist in Berkeley Lab’s Materials Sciences Division.

The work was supported by the DOE Office of Science.

See the full article here .

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In the world of science, Lawrence Berkeley National Laboratory (Berkeley Lab) is synonymous with “excellence.” Thirteen Nobel prizes are associated with Berkeley Lab. Seventy Lab scientists are members of the National Academy of Sciences (NAS), one of the highest honors for a scientist in the United States. Thirteen of our scientists have won the National Medal of Science, our nation’s highest award for lifetime achievement in fields of scientific research. Eighteen of our engineers have been elected to the National Academy of Engineering, and three of our scientists have been elected into the Institute of Medicine. In addition, Berkeley Lab has trained thousands of university science and engineering students who are advancing technological innovations across the nation and around the world.

Berkeley Lab is a member of the national laboratory system supported by the U.S. Department of Energy through its Office of Science. It is managed by the University of California (UC) and is charged with conducting unclassified research across a wide range of scientific disciplines. Located on a 202-acre site in the hills above the UC Berkeley campus that offers spectacular views of the San Francisco Bay, Berkeley Lab employs approximately 3,232 scientists, engineers and support staff. The Lab’s total costs for FY 2014 were $785 million. A recent study estimates the Laboratory’s overall economic impact through direct, indirect and induced spending on the nine counties that make up the San Francisco Bay Area to be nearly $700 million annually. The Lab was also responsible for creating 5,600 jobs locally and 12,000 nationally. The overall economic impact on the national economy is estimated at $1.6 billion a year. Technologies developed at Berkeley Lab have generated billions of dollars in revenues, and thousands of jobs. Savings as a result of Berkeley Lab developments in lighting and windows, and other energy-efficient technologies, have also been in the billions of dollars.

Berkeley Lab was founded in 1931 by Ernest Orlando Lawrence, a UC Berkeley physicist who won the 1939 Nobel Prize in physics for his invention of the cyclotron, a circular particle accelerator that opened the door to high-energy physics. It was Lawrence’s belief that scientific research is best done through teams of individuals with different fields of expertise, working together. His teamwork concept is a Berkeley Lab legacy that continues today.

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From SLAC Lab: “In materials hit with light, individual atoms and vibrations take disorderly paths”


From SLAC Lab

November 1, 2018
Glennda Chui

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Two studies with a new X-ray laser technique reveal for the first time how individual atoms and vibrations respond when a material is hit with light. Their surprisingly unpredictable behavior has profound implications for designing and controlling materials. (Greg Stewart/SLAC National Accelerator Laboratory)

Revealed for the first time by a new X-ray laser technique, their surprisingly unruly response has profound implications for designing and controlling materials.

Hitting a material with laser light sends vibrations rippling through its latticework of atoms, and at the same time can nudge the lattice into a new configuration with potentially useful properties – turning an insulator into a metal, for instance.

Until now, scientists assumed this all happened in a smooth, coordinated way. But two new studies show it doesn’t: When you look beyond the average response of atoms and vibrations to see what they do individually, the response, they found, is disorderly.

Atoms don’t move smoothly into their new positions, like band members marching down a field; they stagger around like partiers leaving a bar at closing time.

And laser-triggered vibrations don’t simply die out; they trigger smaller vibrations that trigger even smaller ones, spreading out their energy in the form of heat, like a river branching into a complex network of streams and rivulets.

This unpredictable behavior at a tiny scale, measured for the first time with a new X-ray laser technique at the Department of Energy’s SLAC National Accelerator Laboratory, will have to be taken into account from now on when studying and designing new materials, the researchers said – especially quantum materials with potential applications in sensors, smart windows, energy storage and conversion and super-efficient electrical conductors.

Two separate international teams, including researchers at SLAC and Stanford University who developed the technique, reported the results of their experiments Sept. 20 in Physical Review Letters and today in Science.

“The disorder we found is very strong, which means we have to rethink how we study all of these materials that we thought were behaving in a uniform way,” said Simon Wall, an associate professor at the Institute of Photonic Sciences in Barcelona and one of three leaders of the study reported in Science. “If our ultimate goal is to control the behavior of these materials so we can switch them back and forth from one phase to another, it’s much harder to control the drunken choir than the marching band.”

Lifting the haze

The classic way to determine the atomic structure of a molecule, whether from a manmade material or a human cell, is to hit it with X-rays, which bounce off and scatter into a detector. This creates a pattern of bright dots, called Bragg peaks, that can be used to reconstruct how its atoms are arranged.

SLAC’s Linac Coherent Light Source (LCLS), with its super-bright and ultrafast X-ray laser pulses, has allowed scientists to determine atomic structures in ever more detail.

SLAC/LCLS

They can even take rapid-fire snapshots of chemical bonds breaking, for instance, and string them together to make “molecular movies.”

About a dozen years ago, David Reis, a professor at SLAC and Stanford and investigator at the Stanford Institute for Materials and Energy Sciences (SIMES), wondered if a faint haze between the bright spots in the detector – 10,000 times weaker than those bright spots, and considered just background noise – could also contain important information about rapid changes in materials induced by laser pulses.

He and SIMES scientist Mariano Trigo went on to develop a technique called “ultrafast diffuse scattering” that extracts information from the haze to get a more complete picture of what’s going on and when.

The two new studies represent the first time the technique has been used to observe details of how energy dissipates in materials and how light triggers a transition from one phase, or state, of a material to another, said Reis, who along with Trigo is a co-author of both papers. These responses are interesting both for understanding the basic physics of materials and for developing applications that use light to switch the properties of materials on and off or convert heat to electricity, for instance.

“It’s sort of like astronomers studying the night sky,” said Olivier Delaire, an associate professor at Duke University who helped lead one of the studies. “Previous studies could only see the brightest stars visible to the naked eye. But with the ultrabright and ultrafast X-ray pulses, we were able to see the faint and diffuse signals of the Milky Way galaxy between them.”

Tiny bells and piano strings

In the study published in Physical Review Letters, Reis and Trigo led a team that investigated vibrations called phonons that rattle the atomic lattice and spread heat through a material.

The researchers knew going in that phonons triggered by laser pulses decay, releasing their energy throughout the atomic lattice. But where does all that energy go? Theorists proposed that each phonon must trigger other, smaller phonons, which vibrate at higher frequencies and are harder to detect and measure, but these had never been seen in an experiment.

To study this process at LCLS, the team hit a thin film of bismuth with a pulse of optical laser light to set off phonons, followed by an X-ray laser pulse about 50 quadrillionths of a second later to record how the phonons evolved. The experiments were led by graduate student Tom Henighan and postdoctoral researcher Samuel Teitelbaum of the Stanford PULSE Institute.

For the first time, Trigo said, they were able to observe and measure how the initial phonons distributed their energy over a wider area by triggering smaller vibrations. Each of those small vibrations emanated from a distinct patch of atoms, and the size of the patch – whether it contained 7 atoms, or 9, or 20 – determined the frequency of the vibration. It was much like how ringing a big bell sets smaller bells tinkling nearby, or how plucking a piano string sets other strings humming.

“This is something we’ve been waiting years to be able to do, so we were excited,” Reis said. “It’s a measurement of something absolutely fundamental to modern solid-state physics, for everything from how heat flows in materials to even, in principle, how light-induced superconductivity emerges, and it could not have been done without an X-ray free-electron laser like LCLS.”

A disorderly march

The paper in Science describes LCLS experiments with vanadium dioxide, a well-studied material that can flip from being an insulator to an electrical conductor in just 100 quadrillionths of a second.

Researchers already knew how to trigger this switch with very short, ultrafast pulses of laser light. But until now they could only observe the average response of the atoms, which seemed to shuffle into their new positions in an orderly way, said Delaire, who led the study with Wall and Trigo.

The new round of diffuse scattering experiments at LCLS showed otherwise. By hitting the vanadium dioxide with an optical laser of just the right energy, the researchers were able to trigger a substantial rearrangement of the vanadium atoms. They did this more than 100 times per second while recording the movements of individual atoms with the LCLS X-ray laser. They discovered that each atom followed an independent, seemingly random path to its new lattice position. Computer simulations by Duke graduate student Shan Yang backed up that conclusion.

“Our findings suggest that disorder may play an important role in some materials,” the team wrote in the Science paper. While this may complicate efforts to control the way materials shift from one phase to another, they added, “it could ultimately provide a new perspective on how to control matter,” and even suggest a new way to induce superconductivity with light.

In a commentary accompanying the report in Science, Andrea Cavalleri of Oxford University and the Max Planck Institute for the Structure and Dynamics of Matter said the results imply that molecular movies of atoms changing position over time don’t paint a complete picture of the microscopic physics involved.

He added, “More generally, it is clear from this work that x-ray free electron lasers are opening up far more than what was envisaged when these machines were being planned, forcing us to reevaluate many old notions taken for granted up to now.”

The study published in PRL also involved researchers from Imperial College London; Tyndall National Institute in Ireland; and the University of Michigan, Ann Arbor. Preliminary measurements were performed at SLAC’s Stanford Synchrotron Radiation Lightsource (SSRL). Major funding came from the DOE Office of Science.

SLAC/SSRL

The study published in Science also involved researchers at the Japan Synchrotron Radiation Research Institute and the DOE’s Oak Ridge National Laboratory. Calculations were performed using resources of the DOE’s National Energy Research Scientific Computing Center (NERSC), and computer simulations used resources of the Oak Ridge Leadership Computing Facility. Major funding came from the European Research Council under the European Union’s Horizon 2020 research and innovation program and from the DOE Office of Science.

LCLS, SSRL and NERSC are DOE Office of Science user facilities.

See the full article here .

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From SLAC National Accelerator Lab: “Scientists make first detailed measurements of key factors related to high-temperature superconductivity”

From SLAC National Accelerator Lab

October 31, 2018
Glennda Chui

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A new study reveals how coordinated motions of copper (red) and oxygen (grey) atoms in a high-temperature superconductor boost the superconducting strength of pairs of electrons (white glow), allowing the material to conduct electricity without any loss at much higher temperatures. The discovery opens a new path to engineering higher-temperature superconductors. (Greg Stewart/SLAC National Accelerator Laboratory)

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An illustration depicts the repulsive energy (yellow flashes) generated by electrons in one layer of a cuprate material repelling electrons in the next layer. Theorists think this energy could play a critical role in creating the superconducting state, leading electrons to form a distinctive form of “sound wave” that could boost superconducting temperatures. Scientists have now observed and measured those sound waves for the first time. (Greg Stewart/SLAC National Accelerator Laboratory)

In superconducting materials, electrons pair up and condense into a quantum state that carries electrical current with no loss. This usually happens at very low temperatures. Scientists have mounted an all-out effort to develop new types of superconductors that work at close to room temperature, which would save huge amounts of energy and open a new route for designing quantum electronics. To get there, they need to figure out what triggers this high-temperature form of superconductivity and how to make it happen on demand.

Now, in independent studies reported in Science and Nature, scientists from the Department of Energy’s SLAC National Accelerator Laboratory and Stanford University report two important advances: They measured collective vibrations of electrons for the first time and showed how collective interactions of the electrons with other factors appear to boost superconductivity.

Carried out with different copper-based materials and with different cutting-edge techniques, the experiments lay out new approaches for investigating how unconventional superconductors operate.

“Basically, what we’re trying to do is understand what makes a good superconductor,” said co-author Thomas Devereaux, a professor at SLAC and Stanford and director of SIMES, the Stanford Institute for Materials and Energy Sciences, whose investigators led both studies.

“What are the ingredients that could give rise to superconductivity at temperatures well above what they are today?” he said. “These and other recent studies indicate that the atomic lattice plays an important role, giving us hope that we are gaining ground in answering that question.”

The high-temperature puzzle

Conventional superconductors were discovered in 1911, and scientists know how they work: Free-floating electrons are attracted to a material’s lattice of atoms, which has a positive charge, in a way that lets them pair up and flow as electric current with 100 percent efficiency. Today, superconducting technology is used in MRI machines, maglev trains and particle accelerators.

But these superconductors work only when chilled to temperatures as cold as outer space. So when scientists discovered in 1986 that a family of copper-based materials known as cuprates can superconduct at much higher, although still quite chilly, temperatures, they were elated.

The operating temperature of cuprates has been inching up ever since – the current record is about 120 degrees Celsius below the freezing point of water – as scientists explore a number of factors that could either boost or interfere with their superconductivity. But there’s still no consensus about how the cuprates function.

“The key question is how can we make all these electrons, which very much behave as individuals and do not want to cooperate with others, condense into a collective state where all the parties participate and give rise to this remarkable collective behavior?” said Zhi-Xun Shen, a SLAC/Stanford professor and SIMES investigator who participated in both studies.

Behind-the-scenes boost

One of the new studies, at SLAC’s Stanford Synchrotron Radiation Lightsource (SSRL), took a systematic look at how “doping” – adding a chemical that changes the density of electrons in a material – affects the superconductivity and other properties of a cuprate called Bi2212.

SLAC/SSRL


SLAC/SSRL

Collaborating researchers at the National Institute of Advanced Industrial Science and Technology (AIST) in Japan prepared samples of the material with slightly different levels of doping. Then a team led by SIMES researcher Yu He and SSRL staff scientist Makoto Hashimoto examined the samples at SSRL with angle-resolved photoemission spectroscopy, or ARPES. It uses a powerful beam of X-ray light to kick individual electrons out of a sample material so their momentum and energy can be measured. This reveals what the electrons in the material are doing.

In this case, as the level of doping increased, the maximum superconducting temperature of the material peaked and fell off again, He said.

The team focused in on samples with particularly robust superconducting properties. They discovered that three interwoven effects – interactions of electrons with each other, with lattice vibrations and with superconductivity itself – reinforce each other in a positive feedback loop when conditions are right, boosting superconductivity and raising the superconducting temperature of the material.

Small changes in doping produced big changes in superconductivity and in the electrons’ interaction with lattice vibrations, Devereaux said. The next step is to figure out why this particular level of doping is so important.

“One popular theory has been that rather than the atomic lattice being the source of the electron pairing, as in conventional superconductors, the electrons in high-temperature superconductors form some kind of conspiracy by themselves. This is called electronic correlation,” Yu He said. “For instance, if you had a room full of electrons, they would spread out. But if some of them demand more individual space, others will have to squeeze closer to accommodate them.”

In this study, He said, “What we find is that the lattice has a behind-the-scenes role after all, and we may have overlooked an important ingredient for high-temperature superconductivity for the past three decades,” a conclusion that ties into the results of earlier research by the SIMES group Science.

Electron ‘Sound Waves’

The other study, performed at the European Synchrotron Radiation Facility (ESRF) in France, used a technique called resonant inelastic X-ray scattering, or RIXS, to observe the collective behavior of electrons in layered cuprates known as LCCO and NCCO.


ESRF. Grenoble, France

RIXS excites electrons deep inside atoms with X-rays, and then measures the light they give off as they settle back down into their original spots.

In the past, most studies have focused only on the behavior of electrons within a single layer of cuprate material, where electrons are known to be much more mobile than they are between layers, said SIMES staff scientist Wei-Sheng Lee. He led the study with Matthias Hepting, who is now at the Max Planck Institute for Solid State Research in Germany.

But in this case, the team wanted to test an idea raised by theorists – that the energy generated by electrons in one layer repelling electrons in the next one plays a critical role in forming the superconducting state.

When excited by light, this repulsion energy leads electrons to form a distinctive sound wave known as an acoustic plasmon, which theorists predict could account for as much as 20 percent of the increase in superconducting temperature seen in cuprates.

With the latest in RIXS technology, the SIMES team was able to observe and measure those acoustic plasmons.

“Here we see for the first time how acoustic plasmons propagate through the whole lattice,” Lee said. “While this doesn’t settle the question of where the energy needed to form the superconducting state comes from, it does tell us that the layered structure itself affects how the electrons behave in a very profound way.”

This observation sets the stage for future studies that manipulate the sound waves with light, for instance, in a way that enhances superconductivity, Lee said. The results are also relevant for developing future plasmonic technology, he said, with a range of applications from sensors to photonic and electronic devices for communications.

SSRL is a DOE Office of Science user facility, and SIMES is a joint institute of SLAC and Stanford.

In addition to researchers from SLAC, Stanford and AIST, the study carried out at SSRL involved scientists from University of Tokyo; University of California, Berkeley; and Lorentz Institute for Theoretical Physics in the Netherlands.

The study conducted at ESRF also involved researchers from SSRL; Polytechnic University of Milan in Italy; ESRF; Binghamton University in New York; and the University of Maryland.

Both studies were funded by the DOE Office of Science.

See the full article here .


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From Brookhaven National Lab: “‘Choosy’ Electronic Correlations Dominate Metallic State of Iron Superconductor”

From Brookhaven National Lab

October 3, 2018
Ariana Tantillo
atantillo@bnl.gov

Finding could lead to a universal explanation of how two radically different types of materials—an insulator and a metal—can perfectly carry electrical current at relatively high temperatures.

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Scientists discovered strong electronic correlations in certain orbitals, or energy shells, in the metallic state of the high-temperature superconductor iron selenide (FeSe). A schematic of the arrangement of the Se and Fe atoms is shown on the left; on the right is an image of the Se atoms in the termination layer of an FeSe crystal. Only the electron orbitals from the Fe atoms contribute to the orbital selectivity in the metallic state.

Two families of high-temperature superconductors (HTS)—materials that can conduct electricity without energy loss at unusually high (but still quite cold) temperatures—may be more closely related than scientists originally thought.

Beyond their layered crystal structures and the fact that they become superconducting when “doped” with atoms of other elements and cooled to a critical temperature, copper-based and iron-based HTS seemingly have little in common. After all, one material is normally an insulator (copper-based), and the other is a metal (iron-based). But a multi-institutional team of scientists has now presented new evidence suggesting that these radically different materials secretly share an important feature: strong electronic correlations. Such correlations occur when electrons move together in a highly coordinated way.

“Theory has long predicted that strong electronic correlations can remain hidden in plain sight in a Hund’s metal,” said team member J.C. Seamus Davis, a physicist in the Condensed Matter Physics and Materials Science at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and the James Gilbert White Distinguished Professor in the Physical Sciences at Cornell University. “A Hund’s metal is a unique new type of electronic fluid in which the electrons from different orbitals, or energy shells, maintain very different degrees of correlation as they move through the material. By visualizing the orbital identity and correlation strength for different electrons in the metal iron selenide (FeSe), we discovered that orbital-selective strong correlations are present in this iron-based HTS.”

It is yet to be determined if such correlations are characteristic of iron-based HTS in general. If proven to exist across both families of materials, they would provide the universal key ingredient in the recipe for high-temperature superconductivity. Finding this recipe has been a holy grail of condensed matter physics for decades, as it is key to developing more energy-efficient materials for medicine, electronics, transportation, and other applications.

Experiment meets theory

Since the discovery of iron-based HTS in 2008 (more than 20 years after that of copper-based HTS), scientists have been trying to understand the behavior of these unique materials. Confusion arose immediately because high-temperature superconductivity in copper-based materials emerges from a strongly correlated insulating state, but in iron-based HTS, it always emerges from a metallic state that lacks direct signatures of correlations. This distinction suggested that strong correlations were not essential—or perhaps even relevant—to high-temperature superconductivity. However, advanced theory soon provided another explanation. Because Fe-based materials have multiple active Fe orbitals, intense electronic correlations could exist but remain hidden due to orbital selectivity in the Hund’s metal state, yet still generate high-temperature superconductivity.

In this study, recently described in Nature Materials, the team—including Brian Andersen of Copenhagen University, Peter Hirschfeld of the University of Florida, and Paul Canfield of DOE’s Ames National Laboratory—used a scanning tunneling microscope to image the quasiparticle interference of electrons in FeSe samples synthesized and characterized at Ames National Lab. Quasiparticle interference refers to the wave patterns that result when electrons are scattered due to atomic-scale defects—such as impurity atoms or vacancies—in the crystal lattice.

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The spectroscopic imaging scanning tunneling microscope used for this study, in three different views.

Spectroscopic imaging scanning tunneling microcopy can be used to visualize these interference patterns, which are characteristic of the microscopic behavior of electrons. In this technique, a single-atom probe moves back and forth very close to the sample’s surface in extremely tiny steps (as small as two trillionths of a meter) while measuring the amount of electrical current that is flowing between the single atom on the probe tip and the material, under an applied voltage.

Their analysis of the interference patterns in FeSe revealed that the electronic correlations are orbitally selective—they depend on which orbital each electron comes from. By measuring the strength of the electronic correlations (i.e., amplitude of the quasiparticle interference patterns), they determined that some orbitals show very weak correlation, whereas others show very strong correlation.

The next question to investigate is whether the orbital-selective electronic correlations are related to superconductivity. If the correlations act as a “glue” that binds electrons together into the pairs required to carry superconducting current—as is thought to happen in the copper-oxide HTS—a single picture of high-temperature superconductivity may emerge.

Experimental studies were carried out by the former Center for Emergent Superconductivity, a DOE Energy Frontier Research Center at Brookhaven, and the research was supported by DOE’s Office of Science, the Moore Foundation’s Emergent Phenomena in Quantum Physics (EPiQS) Initiative, and a Lundbeckfond Fellowship.

See the full article here .


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One of ten national laboratories overseen and primarily funded by the Office of Science of the U.S. Department of Energy (DOE), Brookhaven National Laboratory conducts research in the physical, biomedical, and environmental sciences, as well as in energy technologies and national security. Brookhaven Lab also builds and operates major scientific facilities available to university, industry and government researchers. The Laboratory’s almost 3,000 scientists, engineers, and support staff are joined each year by more than 5,000 visiting researchers from around the world. Brookhaven is operated and managed for DOE’s Office of Science by Brookhaven Science Associates, a limited-liability company founded by Stony Brook University, the largest academic user of Laboratory facilities, and Battelle, a nonprofit, applied science and technology organization.
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