From phys.org: “Electricity from seawater: New method efficiently produces hydrogen peroxide for fuel cells”
May 20, 2016
Credit: Mr. William Folsom, NOAA, NMFS
Scientists have used sunlight to turn seawater (H2O) into hydrogen peroxide (H2O2), which can then be used in fuel cells to generate electricity. It is the first photocatalytic method of H2O2 production that achieves a high enough efficiency so that the H2O2 can be used in a fuel cell.
The researchers, led by Shunichi Fukuzumi at Osaka University, have published a paper* on the new method of the photocatalytic production of hydrogen peroxide in a recent issue of Nature Communications.
“The most earth-abundant resource, seawater, is utilized to produce a solar fuel that is H2O2,” Fukuzumi told Phys.org.
The biggest advantage of using liquid H2O2 instead of gaseous hydrogen (H2), as most fuel cells today use, is that the liquid form is much easier to store at high densities. Typically, H2 gas must be either highly compressed, or in certain cases, cooled to its liquid state at cryogenic temperatures. In contrast, liquid H2O2 can be stored and transported at high densities much more easily and safely.
The problem is that that, until now, there has been no efficient photocatalytic method of producing liquid H2O2. (There are ways to produce H2O2 that don’t use sunlight, but they require so much energy that they are not practical for use in a method whose goal is to produce energy.)
In the new study, the researchers developed a new photoelectrochemical cell, which is basically a solar cell that produces H2O2. When sunlight illuminates the photocatalyst, the photocatalyst absorbs photons and uses the energy to initiate chemical reactions (seawater oxidation and the reduction of O2) in a way that ultimately produces H2O2.
After illuminating the cell for 24 hours, the concentration of H2O2 in the seawater reached about 48 mM, which greatly exceeds previous reported values of about 2 mM in pure water. Investigating the reason for this big difference, the researchers found that the negatively charged chlorine in seawater is mainly responsible for enhancing the photocatalytic activity and yielding the higher concentration.
Overall, the system has a total solar-to-electricity efficiency of 0.28%. (The photocatalytic production of H2O2 from seawater has an efficiency of 0.55%, and the fuel cell has an efficiency of 50%.)
Although the total efficiency compares favorably to that of some other solar-to-electricity sources, such as switchgrass (0.2%), it is still much lower than the efficiency of conventional solar cells. The researchers expect that the efficiency can be improved in the future by using better materials in the photoelectrochemical cell, and they also plan to find methods to reduce the cost of production.
“In the future, we plan to work on developing a method for the low-cost, large-scale production of H2O2 from seawater,” Fukuzumi said. “This may replace the current high-cost production of H2O2 from H2 (from mainly natural gas) and O2.”
See the full article here .
Please help promote STEM in your local schools.
About Phys.org in 100 Words
Phys.org™ (formerly Physorg.com) is a leading web-based science, research and technology news service which covers a full range of topics. These include physics, earth science, medicine, nanotechnology, electronics, space, biology, chemistry, computer sciences, engineering, mathematics and other sciences and technologies. Launched in 2004, Phys.org’s readership has grown steadily to include 1.75 million scientists, researchers, and engineers every month. Phys.org publishes approximately 100 quality articles every day, offering some of the most comprehensive coverage of sci-tech developments world-wide. Quancast 2009 includes Phys.org in its list of the Global Top 2,000 Websites. Phys.org community members enjoy access to many personalized features such as social networking, a personal home page set-up, RSS/XML feeds, article comments and ranking, the ability to save favorite articles, a daily newsletter, and other options.