From Aalto University [Aalto-yliopisto] (FI): “Controlling quantum states in individual molecules with two-dimensional ferroelectrics”
From Aalto University [Aalto-yliopisto] (FI)
1.9.23
Researchers demonstrated how to control the quantum states of individual molecules with an electrically controllable substrate.
Jose Lado
Assistant Professor
T304 Dept. Applied Physics
jose.lado@aalto.fi
+358503133730
Adam Foster
Professori
adam.foster@aalto.fi
Peter Liljeroth
Akatemiaprofessori
peter.liljeroth@aalto.fi
+358503636115
Researchers used electricity to control the internal states of molecules. Image: Jose Lado/Aalto University.
Controlling the internal states of quantum systems is one of the biggest challenges in quantum materials. At the deepest level, single molecules can display different quantum states even while possessing the same number of electrons. These states are associated with different electron configurations, which can lead to dramatically different properties.
The capability of controlling the electronic configuration of single molecules could lead to major developments in both fundamental science and technology. On the one hand, controlling the internal states of molecules may allow for the development of new artificial materials with exotic properties. On the other hand, it might also make possible the ultimate miniaturization of classical computer memories, with the two configurations could make it possible to encode a 0 and a 1 in a classical memory unit at the molecular level. However, controlling the internal states of molecules still remains a challenge, and realistic, scalable strategies for overcoming it have not been proposed.
Tuning internal states by applying voltage
In a recent experimental breakthrough researchers from Aalto University and the University of Jyväskylä demonstrated the ability to control the quantum states of individual molecules with an electrically controllable substrate. Their experiment showed how a specific two-dimensional material, known as SnTe, provides the instrumental strategy needed to control molecular states.
The mechanism demonstrated by the researchers is based on the ability of a substrate to tune the internal state of molecules due to internal electric fields. This mechanism, known as “ferroelectric molecular switching”, enables researchers to control individual molecules merely by applying a voltage to the substrate. The strategy relies on the strong tunability of SnTe by external voltages, which stems from a unique quantum property known as ferroelectricity.
The research team involved the groups of Professors Peter Liljeroth, Adam Foster, and Jose Lado from Aalto University, and the team was led by Professor Shawulienu Kezilebieke from the University of Jyväskylä.
‘Our results demonstrate how we can control individual molecules using electrically-tunable two-dimensional materials. From a practical point of view, two-dimensional ferroelectrics have been instrumental, as its ultraclean interface allows realizing this strategy of quantum control. These experiments put forward a strategy to engineer quantum states at the molecular level, opening exciting possibilities in artificial materials and single-molecule electronics,’ Kezilebieke says.
‘In our experiments, we demonstrated how two-dimensional ferroelectrics allow us to realize electrically switchable quantum states. Controlling quantum states electrically is a major milestone in quantum materials, and here we demonstrated one strategy for doing it at the deepest level of individual molecules,’ says PhD researcher Mohammad Amini, the first author of the study.
The quantum control of molecules via substrate effects opens up new possibilities in quantum matter, including engineering artificial molecular materials with switchable states. The research was recently published in Advanced Materials.
See the science paper for instructive material with images.
See the full article here.
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Aalto University [Aalto-yliopisto] (FI) is a university located in Espoo, Finland. It was established in 2010 as a merger of three major Finnish universities: the Helsinki University of Technology (established 1849), the Helsinki School of Economics (established 1904), and the University of Art and Design Helsinki (established 1871). The close collaboration between the scientific, business and arts communities is intended to foster multi-disciplinary education and research. The Finnish government, in 2010, set out to create a university that fosters innovation, merging the three institutions into one.
The university is composed of six schools with close to 17,500 students and 4,000 staff members, making it Finland’s second largest university. The main campus of Aalto University is located in Otaniemi, Espoo. Aalto University Executive Education operates in the district of Töölö, Helsinki. In addition to the Greater Helsinki area, the university also operates its Bachelor’s Programme in International Business in Mikkeli and the Metsähovi Radio Observatory Metsähovi Radio Observatory [Metsähovin radiotutkimusasema] Aalto University [Aalto-yliopisto](FI) in Kirkkonummi. in Kirkkonummi.
Aalto University’s operations showcase Finland’s experiment in higher education. The Aalto Design Factory, Aalto Ventures Program and Aalto Entrepreneurship Society (Aaltoes), among others, drive the university’s mission for a radical shift towards multidisciplinary learning and have contributed substantially to the emergence of Helsinki as a hotbed for startups. Aaltoes is Europe’s largest and most active student run entrepreneurship community that has founded major concepts such as the Startup Sauna accelerator program and the Slush startup event.
The university is named in honour of Alvar Aalto, a prominent Finnish architect, designer and alumnus of the former Helsinki University of Technology, who was also instrumental in designing a large part of the university’s main campus in Otaniemi.
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