From Harvard Engineering and Applied Sciences and Wyss Institute of Biologically Inspired Engineeringvia phys.org: “Sculpting optical microstructures with slight changes in chemistry”

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Harvard John A. Paulson School of Engineering and Applied Sciences

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phys.org

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A mathematical model (left) uses a geometrical framework to explain how previous patterns grew and predict new carbonate-silica structures (right, imaged by scanning electron microscopy). Credit: Wim L. Noorduin/ C. Nadir Kaplan/ Harvard University

In 2013, materials scientists at the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) and the Wyss Institute of Biologically Inspired Engineering, grew a garden of self-assembled crystal microstructures. Now, applied mathematicians at SEAS and Wyss have developed a framework to better understand and control the fabrication of these microstructures.

Together, the researchers used that framework to grow sophisticated optical microcomponents.

The research is published in Science.

When it comes to the fabrication of multifunctional materials, nature has humans beat by miles. Marine mollusks can embed photonic structures into their curved shells without compromising shell strength; deep sea sponges evolved fiber optic cables to direct light to symbiotically living organisms; and brittlestars cover their skeletons with lenses to focus light into the body to “see” at night. During growth, these sophisticated optical structures tune tiny, well-defined curves and hollow shapes to better guide and trap light.

Manufacturing complex bio-inspired shapes in the lab is often time consuming and costly. The breakthrough in 2013 was led by materials scientists Joanna Aizenberg, the Amy Smith Berylson Professor of Materials Science and Chemistry and Chemical Biology and core faculty member of the Wyss Institute and former postdoctoral fellow Wim L. Noorduin. The research allowed researchers to fabricate delicate, flower-like structures on a substrate by simply manipulating chemical gradients in a beaker of fluid. These structures, composed of carbonate and glass, form a bouquet of thin walls.

What that research lacked then was a quantitative understanding of the mechanisms involved that would enable even more precise control over these structures.

Enter the theorists.

Inspired by the theory to explain solidification and crystallization patterns, L. Mahadevan, the Lola England de Valpine Professor of Applied Mathematics, Physics, and Organismic and Evolutionary Biology, and postdoctoral fellow C. Nadir Kaplan, developed a new geometrical framework to explain how previous precipitation patterns grew and even predicted new structures.

Mahadevan is also core member of the Wyss Institute.

In experiments, the shape of the structures can be controlled by changing the pH of the solution in which the shapes are fabricated.

“At high pH, these structures grow in a flat manner and you get flat shapes, like side of a vase,” said Kaplan, co-first author of the paper. “At low pH, the structure starts to curve and you get helical structures.”

When Kaplan solved the resulting equations as a function of pH, with a mathematical parameter standing in for the chemical change, he found that he could recreate all the shapes developed by Noorduin and Aizenberg—and come up with new ones.

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Researchers used a new framework to grow sophisticated optical microcomponents, including trumpet-shaped assemblages that operate as waveguides. Credit: Wim L. Noorduin/Harvard University

“Once we understood the growth and form of these structures and we could quantify them; our goal was to use the theory to come up with a strategy to build optical structures from the bottom up,” said Kaplan.

Kaplan and Noorduin worked together to grow resonators, waveguides and beam splitters.

“When we had the theoretical framework, we were able to show the same process experimentally,” said Noorduin, co-first author. “Not only were we able to grow these microstructures, but we could also demonstrate their ability to conduct light.”

Noorduin is now a group lead at the Dutch materials research organization AMOLF.

“The approach may provide a scalable, inexpensive and accurate strategy to fabricate complex three-dimensional microstructures, which cannot be made by top-down manufacturing and tailor them for magnetic, electronic, or optical applications,” said Joanna Aizenberg, co-author of the paper.

“Our theory reveals that, in addition to growth, carbonate-silica structures can also undergo bending along the edge of their thin walls,” said Mahadevan, the senior author of the paper. “This additional degree of freedom is typically lacking in conventional crystals, such as a growing snowflake. This points to a new kind of growth mechanism in mineralization, and because the theory is independent of absolute scale, it may be adapted to other geometrically constrained growth phenomena in physical and biological systems.”

Next, the researchers hope to model how groups of these structures compete against each other for chemicals, like trees in a forest competing for sunlight.

See the full article here .

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The Wyss (pronounced “Veese”) Institute for Biologically Inspired Engineering uses Nature’s design principles to develop bioinspired materials and devices that will transform medicine and create a more sustainable world.

Working as an alliance among Harvard’s Schools of Medicine, Engineering, and Arts & Sciences, and in partnership with Beth Israel Deaconess Medical Center, Boston Children’s Hospital, Brigham and Women’s Hospital, Dana Farber Cancer Institute, Massachusetts General Hospital, the University of Massachusetts Medical School, Spaulding Rehabilitation Hospital, Tufts University, and Boston University, the Institute crosses disciplinary and institutional barriers to engage in high-risk research that leads to transformative technological breakthroughs.

Through research and scholarship, the Harvard School of Engineering and Applied Sciences (SEAS) will create collaborative bridges across Harvard and educate the next generation of global leaders. By harnessing the power of engineering and applied sciences we will address the greatest challenges facing our society.

Specifically, that means that SEAS will provide to all Harvard College students an introduction to and familiarity with engineering and technology as this is essential knowledge in the 21st century.

Moreover, our concentrators will be immersed in the liberal arts environment and be able to understand the societal context for their problem solving, capable of working seamlessly withothers, including those in the arts, the sciences, and the professional schools. They will focus on the fundamental engineering and applied science disciplines for the 21st century; as we will not teach legacy 20th century engineering disciplines.

Instead, our curriculum will be rigorous but inviting to students, and be infused with active learning, interdisciplinary research, entrepreneurship and engineering design experiences. For our concentrators and graduate students, we will educate “T-shaped” individuals – with depth in one discipline but capable of working seamlessly with others, including arts, humanities, natural science and social science.

To address current and future societal challenges, knowledge from fundamental science, art, and the humanities must all be linked through the application of engineering principles with the professions of law, medicine, public policy, design and business practice.

In other words, solving important issues requires a multidisciplinary approach.

With the combined strengths of SEAS, the Faculty of Arts and Sciences, and the professional schools, Harvard is ideally positioned to both broadly educate the next generation of leaders who understand the complexities of technology and society and to use its intellectual resources and innovative thinking to meet the challenges of the 21st century.

Ultimately, we will provide to our graduates a rigorous quantitative liberal arts education that is an excellent launching point for any career and profession.

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