Berkeley Lab Researchers Probe Into Electronic Structure of MOF May Lead to Improved Capturing of Greenhouse Gases
November 22, 2013
Lynn Yarris (510) 486-5375 firstname.lastname@example.org
A unique inside look at the electronic structure of a highly touted metal-organic framework (MOF) as it is adsorbing carbon dioxide gas should help in the design of new and improved MOFs for carbon capture and storage. Researchers with the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) have recorded the first in situ electronic structure observations of the adsorption of carbon dioxide inside Mg-MOF-74, an open metal site MOF that has emerged as one of the most promising strategies for capturing and storing greenhouse gases.
Working at Berkeley Lab’s Advanced Light Source (ALS), a team led by Jeff Kortright of Berkeley Lab’s Materials Sciences Division, used the X-ray spectroscopy technique known as Near Edge X-ray Absorption Fine Structure (NEXAFS) to obtain what are believed to be the first ever measurements of chemical and electronic signatures inside of a MOF during gas adsorption.
“We’ve demonstrated that NEXAFS spectroscopy is an effective tool for the study of MOFs and gas adsorption,” Kortright says. “Our study shows that open metal site MOFs have significant X-ray spectral signatures that are highly sensitive to the adsorption of carbon dioxide and other molecules.”
Kortright is the corresponding author of a paper describing these results in the Journal of the American Chemical Society (JACS). The paper is titled Probing Adsorption Interactions In Metal-Organic Frameworks Using X-ray Spectroscopy. Co-authors are Walter Drisdell, Roberta Poloni, Thomas McDonald, Jeffrey Long, Berend Smit, Jeffrey Neaton and David Prendergast.
Mg-MOF-74 is an open metal site MOF whose porous crystalline structure could enable it to serve as a storage vessel for capturing and containing the carbon dioxide emitted from coal-burning power plants. (National Academy of Sciences)
See the full article here.
A U.S. Department of Energy National Laboratory Operated by the University of California
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